Synthesis of Branched Poly(butylene succinate): Structure Properties Relationship

Marie Vandesteene; Nicolas Jacquel; René Saint-Loup; Boucard Nadège; Carrot Christian; Rousseau Alain; Fenouillot Françoise

doi:10.1007/s10118-016-1805-5

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Synthesis of Branched Poly(butylene succinate): Structure Properties Relationship

PAPERS | Updated：2021-05-12

- Synthesis of Branched Poly(butylene succinate): Structure Properties Relationship
- Chinese Journal of Polymer Science Vol. 34, Issue 7, Pages: 873-888(2016)
- Affiliations：
  
  a.Unive Lyon, INSA-Lyon, Ingénierie des Matériaux Polymères, IMP, UMR5223, F-69621, Villeurbanne, France
  b.Univ Lyon, Université Jean Monnet, Ingénierie des Matériaux Polymères, IMP, UMR5223, F-42023 Saint-Etienne, France
  c.Roquette Frères, Polymer Chemistry Department, F-62136 Lestrem, France
  d.MBD Texinov, F-38110 Saint-Didier-de-la-Tour, France
- Author bio：
  
  Françoise Fenouillot, E-mail: francoise.fenouillot@insa-lyon.fr
- Funds：
- DOI：10.1007/s10118-016-1805-5
  CLC：
- Received：17 January 2016，
  
  Revised：2016-2-22，
  
  Accepted：23 February 2016，
  
  Published：2016-07
- Accepted：
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Marie Vandesteene, Nicolas Jacquel, René Saint-Loup, et al. Synthesis of Branched Poly(butylene succinate): Structure Properties Relationship[J]. Chinese Journal of Polymer Science, 2016, 34(7): 873-888.
DOI：

Marie Vandesteene, Nicolas Jacquel, René Saint-Loup, et al. Synthesis of Branched Poly(butylene succinate): Structure Properties Relationship[J]. Chinese Journal of Polymer Science, 2016, 34(7): 873-888. DOI： 10.1007/s10118-016-1805-5.

摘要

Abstract

A series of branched poly(butylene succinate) (PBS) were synthesized with several branching agents namely trimethylol propane (TMP)

malic acid

trimesic acid

citric acid and glycerol propoxylate. The structure of the branched polymers was analyzed by SEC and

H-NMR. The effect of branching agent structure on crystallization was also investigated and played a significant role. Isothermal studies showed that glycerol propoxylate could act as a nucleating agent. By contrast high content of TMP disturbed the regularity of the chain and hindered the crystallization of PBS. From the non-isothermal kinetic study

it was found that glycerol propoxylate increased noticeably the crystallization rate due to the flexible structure of the branching agent. A secondary nucleation was observed with glycerol propoxylate attributed to the crystallization of amorphous fraction included between crystallites formed at the primary crystallization. Chain topology was obtained through rheological investigations and the synthesized polymers showed a typical behavior of a mixture of linear and randomly branched PBS. The incorporation of branches improved the processability of PBS for film blowing application and the modulus and the stress at break of the resulting film were significantly increased.

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