Synthesis of Poly[6-(2, 6-bis(1'-methylbenzimidazolyl)pyridin-4-yloxy)hexyl acrylate] (PBIP) and Magnetic Property of Its Neodymium Complex (PBIP-Nd<sup>3+</sup>)

Di-zheng Liu; Wei-lin Sun; Rong Ren; Yan-hua Wang; Zhi-quan Shen

doi:10.1007/s10118-016-1804-6

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Synthesis of Poly[6-(2, 6-bis(1'-methylbenzimidazolyl)pyridin-4-yloxy)hexyl acrylate] (PBIP) and Magnetic Property of Its Neodymium Complex (PBIP-Nd³⁺)

PAPERS | Updated：2021-05-12

- Synthesis of Poly[6-(2, 6-bis(1'-methylbenzimidazolyl)pyridin-4-yloxy)hexyl acrylate] (PBIP) and Magnetic Property of Its Neodymium Complex (PBIP-Nd³⁺)
- Chinese Journal of Polymer Science Vol. 34, Issue 7, Pages: 910-918(2016)
- Affiliations：
  
  MOE Key Laboratory of Macromolecular Synthesis and Functionalization, Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027, China
- Author bio：
  
  Wei-lin Sun (孙维林), E-mail: opl_sunwl@zju.edu.cn
- Funds：
- DOI：10.1007/s10118-016-1804-6
  CLC：
- Received：31 January 2016，
  
  Revised：2016-3-9，
  
  Accepted：14 March 2016，
  
  Published：2016-07
- Accepted：
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Di-zheng Liu, Wei-lin Sun, Rong Ren, et al. Synthesis of Poly[6-(2, 6-bis(1'-methylbenzimidazolyl)pyridin-4-yloxy)hexyl acrylate] (PBIP) and Magnetic Property of Its Neodymium Complex (PBIP-Nd³⁺)[J]. Chinese Journal of Polymer Science, 2016, 34(7): 910-918. DOI: 10.1007/s10118-016-1804-6.
DOI：

Di-zheng Liu, Wei-lin Sun, Rong Ren, et al. Synthesis of Poly[6-(2, 6-bis(1'-methylbenzimidazolyl)pyridin-4-yloxy)hexyl acrylate] (PBIP) and Magnetic Property of Its Neodymium Complex (PBIP-Nd³⁺)[J]. Chinese Journal of Polymer Science, 2016, 34(7): 910-918. DOI: 10.1007/s10118-016-1804-6. DOI：

摘要

Abstract

Homopolymer (PBIP) containing 2

6-bis(1'-methylbenzimidazolyl)pyridine (MeBIP) ligands in the side chain was synthesized by RAFT polymerization and its kinetics was studied. Polymeric complex PBIP-Nd

was prepared by chelating PBIP with lanthanide ion Nd

. The homopolymers and PBIP-Nd

complex were investigated by NMR

FTIR

GPC and TGA. The optical property of PBIP-Nd

complex was characterized by UV-Vis spectroscopy. The magnetic property of PBIP-Nd

complex was measured as a function of temperature (5 K to 300 K) and as a function of field (-3.98 × 10

A/m to 3.98 × 10

A/m). These results indicated that PBIP-Nd

complex is paramagnetic.

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⁰

Synthesis of Poly[6-(2, 6-bis(1'-methylbenzimidazolyl)pyridin-4-yloxy)hexyl acrylate] (PBIP) and Magnetic Property of Its Neodymium Complex (PBIP-Nd3+)

DOI：10.1007/s10118-016-1804-6

摘要

Abstract

关键词

Keywords

references

Synthesis of Poly[6-(2, 6-bis(1'-methylbenzimidazolyl)pyridin-4-yloxy)hexyl acrylate] (PBIP) and Magnetic Property of Its Neodymium Complex (PBIP-Nd³⁺)