Mechanism of Polymorph Selection during Crystallization of Random Butene-1/Ethylene Copolymer

Yao-tao Wang; Pei-ru Liu; Ying Lu; Yong-feng Men

doi:10.1007/s10118-016-1802-8

Your Location：

Home >

Browse articles >

Mechanism of Polymorph Selection during Crystallization of Random Butene-1/Ethylene Copolymer

PAPERS | Updated：2021-05-12

- Mechanism of Polymorph Selection during Crystallization of Random Butene-1/Ethylene Copolymer
- Chinese Journal of Polymer Science Vol. 34, Issue 8, Pages: 1014-1020(2016)
- Affiliations：
  
  State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, University of Chinese Academy of Sciences, Changchun 130022, China
- Author bio：
  
  Yong-feng Men (门永锋), E-mail: men@ciac.ac.cn
- Funds：
- DOI：10.1007/s10118-016-1802-8
  CLC：
- Received：28 February 2016，
  
  Revised：2016-3-3，
  
  Accepted：03 March 2016，
  
  Published：2016-08
- Accepted：
Scan QR Code
Yao-tao Wang, Pei-ru Liu, Ying Lu, et al. Mechanism of Polymorph Selection during Crystallization of Random Butene-1/Ethylene Copolymer[J]. Chinese Journal of Polymer Science, 2016, 34(8): 1014-1020.
DOI：

Yao-tao Wang, Pei-ru Liu, Ying Lu, et al. Mechanism of Polymorph Selection during Crystallization of Random Butene-1/Ethylene Copolymer[J]. Chinese Journal of Polymer Science, 2016, 34(8): 1014-1020. DOI： 10.1007/s10118-016-1802-8.

摘要

Abstract

Starting from an initial sample of butene-1/ethylene copolymer with stable form Ⅰ'

we examined the nucleation of different crystalline polymorphs (here metastable form Ⅱ and stable form Ⅰ') at different isothermal crystallization temperatures after being melted at different melt temperature (

melt

). When

melt

was just above the melting temperature (

) of the crystallites

self-seeding took place. There

residue crystallites served as nuclei leading to the crystallization of the same crystalline phase. When

melt

was a few degrees above the

self-seeding was disabled due to complete melting of the initial crystals. Upon crystallization

the selection of the different polymorphs in this random copolymer was found to depend on an interplay between the domain size of segregated long crystallizable sequences and the size and energy barrier of the critical nucleus of the respective crystalline forms. Our results provide a clear understanding of the polymorphs selection during crystallization of a random copolymer as well as homo-polymers under confinement.

关键词

Keywords

references

G. Strobl . "The physics of polymers" , 2nd ed. : Springer Berlin, Germany , 1997 .

P.J. Flory , D.Y. Yoon . . Nature , 1978 . 272 226 DOI: 10.1038/272226a0 http://doi.org/10.1038/272226a0 .

Wunderlich, B., "Macromolecular physics", Vol. 2, Academic Press, New York, 1976

G. Reiter , J.U. Sommer . . Phys. Rev. Lett. , 1998 . 80 3771 DOI: 10.1103/PhysRevLett.80.3771 http://doi.org/10.1103/PhysRevLett.80.3771 .

G. Reiter , G. Castelein , J.U. Sommer , A. Röttele , T. Thurn-Albrecht . . Phys. Rev. Lett. , 2001 . 87 226101 DOI: 10.1103/PhysRevLett.87.226101 http://doi.org/10.1103/PhysRevLett.87.226101 .

Cheng, S.Z.D., "Phase transitions in polymers:the role of metastable states", Elsevier, Oxford, 2008

G. Alfonso , A. Ziabicki . . Colloid Polym. Sci. , 1995 . 273 317 DOI: 10.1007/BF00652344 http://doi.org/10.1007/BF00652344 .

R. Androsch , B. Wunderlich . . Macromolecules , 2000 . 33 9076 DOI: 10.1021/ma000504h http://doi.org/10.1021/ma000504h .

J.J. Xu , Y. Ma , W.B. Hu , M. Rehahn , G. Reiter . . Nat. Mater. , 2009 . 8 348 DOI: 10.1038/nmat2405 http://doi.org/10.1038/nmat2405 .

B.O. Beid , M. Vadlamudi , A. Mamun , H. Janani , H.H. Gao , W.B. Hu , R.G. Alamo . . Macromolecules , 2013 . 46 6485 DOI: 10.1021/ma400839d http://doi.org/10.1021/ma400839d .

H.H. Gao , M. Vadlamudi , R.G. Alamo , W.B. Hu . . Macromolecules , 2013 . 46 6498 DOI: 10.1021/ma400842h http://doi.org/10.1021/ma400842h .

Y.T. Wang , Y. Lu , J. Zhao , Z.Y. Jiang , Y.F. Men . . Macromolecules , 2014 . 47 8653 DOI: 10.1021/ma5019796 http://doi.org/10.1021/ma5019796 .

F. Danusso . . Polymer , 1967 . 8 281 DOI: 10.1016/0032-3861(67)90031-6 http://doi.org/10.1016/0032-3861(67)90031-6 .

P. Pan , Y. Inoue . . Prog. Polym. Sci. , 2009 . 34 605 DOI: 10.1016/j.progpolymsci.2009.01.003 http://doi.org/10.1016/j.progpolymsci.2009.01.003 .

B. Zhang , D.C. Yang , S.K. Yan . . J. Polym. Sci., Part B:Polym. Phys. , 2002 . 40 2641 DOI: 10.1002/(ISSN)1099-0488 http://doi.org/10.1002/(ISSN)1099-0488 .

N. Blagden , R. Davey . . Cryst. Growth Des. , 2003 . 3 873 DOI: 10.1021/cg030025k http://doi.org/10.1021/cg030025k .

C. Desgranges , J. Delhommelle . . Phys. Rev. Lett. , 2007 . 98 235502 DOI: 10.1103/PhysRevLett.98.235502 http://doi.org/10.1103/PhysRevLett.98.235502 .

M. Yamashita , S. Ueno . . Cryst. Res. Technol. , 2007 . 42 1222 DOI: 10.1002/(ISSN)1521-4079 http://doi.org/10.1002/(ISSN)1521-4079 .

Rosa C. De , F. Auriemma , O. Ruiz de Ballesteros , F. Esposito , D. Laguzza , R. Di Girolamo , L. Resconi . . Macromolecules , 2009 . 42 8286 DOI: 10.1021/ma901453x http://doi.org/10.1021/ma901453x .

A. Turner-Jones . . J. Polym. Sci., Part B:Polym. Lett. , 1963 . 1 455 DOI: 10.1002/pol.1963.110010815 http://doi.org/10.1002/pol.1963.110010815 .

Views

Downloads

CSCD

Alert me when the article has been cited

Submit

Tools

Publicity Resources

Self-nucleation Effect of Crystallization with Various Nucleating Agents

Melt Crystallization of Poly(butylene 2,6-naphthalate)

Two-way Shape Memory Effect of Polycaprolactone-based Polyurethane via Synergistic Role of Hydrogen Bonding and Crystallization Tuned by Malic Acid

Spatially Resolved Cavitation within Tensile Stretched Isotactic Polybutene-1 Spherulite

Pyrimidoisoindigo-based Polymers for Ambipolar Charge Transport

Related Author

Dai Zhang

Rui-Jun Zhao

Gui-Qiu Ma

Zhe Ma

Ruijun Zhao

Zhe Ma

Qian Ding

Michelina Soccio

Related Institution

Tianjin Key Laboratory of Composite and Functional Materials, and School of Materials Science and Engineering, Tianjin University

School of Packaging Design and Art, Hunan University of Technology

Department of Civil, Chemical, Environmental and Materials Engineering, University of Bologna, Via Terracini 28

Department of Chemistry and Industrial Chemistry, University of Genova, Via Dodecaneso 31

Interdisciplinary Center for Transfer-oriented Research in Natural Sciences (IWE TFN), Martin Luther University Halle-Wittenberg, Halle/Saale

⁰