Fabrication and Chemical Crosslinking of Electrospun <italic style="font-style: italic">Trans</italic>-polyisoprene Nanofiber Nonwoven

Nie Hua-rong; Wang Chao; He Ai-hua

doi:10.1007/s10118-016-1796-2

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Fabrication and Chemical Crosslinking of Electrospun Trans-polyisoprene Nanofiber Nonwoven

Papers | Updated：2022-02-21

- Fabrication and Chemical Crosslinking of Electrospun Trans-polyisoprene Nanofiber Nonwoven
- Vol. 34, Issue 6, Pages: 697-708(2016)
- Affiliations：
  
  Shandong Provincial Key Laboratory of Olefin Catalysis and Polymerization, Key Laboratory of Rubber-Plastics (Ministry of Education), School of Polymer Science and Engineering, Qingdao University of Science and Technology, Qingdao 266042, China
- Author bio：
  
  Ai-hua He (贺爱华), E-mail: aihuahe@iccas.ac.cn or ahhe@qust.edu.cn
- Funds：
  
  the National Basic Research Program of China;the National Natural Science Foundation of China;Special Foundation of Taishan Mountain Scholar Constructive Program, Shandong Provincial Key R & D program;Shandong Provincial Natural Science Fund for Distinguished Young Scholars;the Yellow River DeltaScholar program (Office of National University Science & Technology Park Administrative Committee (China University of Petroleum)).()
- DOI：10.1007/s10118-016-1796-2
  CLC：
- Received：30 November 2015，
  
  Revised：2015-12-31，
  
  Accepted：22 January 2016，
  
  Published：2016-06
- Accepted：
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Nie Hua-rong, Wang Chao, He Ai-hua. Fabrication and Chemical Crosslinking of Electrospun Trans-polyisoprene Nanofiber Nonwoven[J]. 2016, 34(6): 697-708. DOI: 10.1007/s10118-016-1796-2.
DOI：

Nie Hua-rong, Wang Chao, He Ai-hua. Fabrication and Chemical Crosslinking of Electrospun Trans-polyisoprene Nanofiber Nonwoven[J]. 2016, 34(6): 697-708. DOI: 10.1007/s10118-016-1796-2. DOI：

摘要

Abstract

In this work

the optimal electrospinning conditions of

trans

-polyisoprene (TPI) solutions were evaluated nevertheless its lower glass transition temperature than the room temperature. Subsequently

chemical crosslinking of TPI nonwovens was firstly investigated by vulcanizing at high temperatures in the case of the persistence of nanofiber structure. For this purpose

curing agents of TPI were embedded in TPI nanofibers by co-electrospinning

and then a protect layer was coated on TPI nanofibers by filtering gelatin solution going through TPI nonwoven before the vulcanization at 140-160 ℃. The results showed that the vulcanization of TPI fibrous nonwoven at high temperatures did not destroy the fiber morphology. Interestingly

TPI fibrous nonwovens after vulcanization showed excellent mechanical properties (~17 MPa of tensile strength) that could be comparable to or even higher than that of some bulk rubber materials.

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Fabrication and Chemical Crosslinking of Electrospun Trans-polyisoprene Nanofiber Nonwoven

DOI：10.1007/s10118-016-1796-2

摘要

Abstract

关键词

Keywords

references