Biodegradable Shape Memory Polyurethanes with Controllable Trigger Temperature

Shu-ying Gu; Xie-feng Gao; Sheng-peng Jin; Liu Yan-liang

doi:10.1007/s10118-016-1795-3

Your Location：

Home >

Browse articles >

Biodegradable Shape Memory Polyurethanes with Controllable Trigger Temperature

Papers | Updated：2022-02-21

- Biodegradable Shape Memory Polyurethanes with Controllable Trigger Temperature
- Vol. 34, Issue 6, Pages: 720-729(2016)
- Affiliations：
  
  aSchool of Materials Science and Engineering, Tongji University, Shanghai 201804, China
  b Key Laboratory of Advanced Civil Engineering Materials, Ministry of Education, Tongji University, Shanghai 201804, China
- Author bio：
  
  Gu Shu-ying，E-mail: gushuying@mail.tongji.edu.cn
- Funds：
  
  the National Key Technology R&D Program
- DOI：10.1007/s10118-016-1795-3
  CLC：
- Received：03 December 2015，
  
  Revised：2015-12-19，
  
  Accepted：22 December 2015，
  
  Published：2016-06
- Accepted：
Scan QR Code
Shu-ying Gu, Xie-feng Gao, Sheng-peng Jin, et al. Biodegradable Shape Memory Polyurethanes with Controllable Trigger Temperature[J]. 2016, 34(6): 720-729.
DOI：

Shu-ying Gu, Xie-feng Gao, Sheng-peng Jin, et al. Biodegradable Shape Memory Polyurethanes with Controllable Trigger Temperature[J]. 2016, 34(6): 720-729. DOI： 10.1007/s10118-016-1795-3.

摘要

Abstract

A series of random copolymers (PCLAs) were synthesized by ring-opening polymerization of

-lactide (LA) and

-caprolactone (CL) with different molar ratios. PCLA based polyurethanes (PCLAUs) were obtained by chain-extending of PCLA and polytetramethylene ether (PTMEG) with hexamethylene diisocyanate (HDI). All the PCLAUs exhibit good shape memory properties with high shape fixity ratios above 98% and shape recovery ratios above 82% in the first cycle and 91% in the second cycle. PCLAUs with less CL content show faster recovery speed and PCLAUs with more CL content show higher shape recovery ratio. The trigger temperature can be tuned or controlled around body temperature by adjusting the molar ratio of LA to CL. The PCLAUs have potential applications in implant biomedical devices

especially for minimally invasive deployable devices.

关键词

Keywords

references

B. Yan , S. Gu , Y. Zhang . Eur. Polym. , 2013 . 49 366 .

Y. Bai , X. Zhang , Q. Wang , T. Wang . Mater. Chem. , 2014 . 2 4771 .

Y.C. Chung , H.Y. Kim , J.W. Choi , B.C. Chun . Macromol. Res. , 2014 . 22 1115 .

Y.C. Chung , J.S. Park , C.H. Shin , J.W. Choi , B.C. Chun . Macromol. Res. , 2012 . 20 66 .

X. Liu , H. Li , Q. Zeng , Y. Zhang , H. Kang , H. Duan , Y. Guo , H. Liu . Mater. Chem., A , 2015 . 3 11641 .

M.Y. Razzaq , M. Behl , K. Kratz , A Lendlein . Adv. Mater. , 2013 . 25 5730 .

L. Yu , L. Wang , J. Sun , C. Li , C. Zou , Z. He , Z. Wang , L. Zhou , L. Zhang , H. Yang . Mater. Chem. A , 2015 . 3 13953 .

A. Lendlein , H. Jiang , O. Jünger , R. Langer . Nature , 2005 . 434 79 .

G. Coativy , N. Gautier , B. Pontoire , Buleon , D. Lourdin , E. Leroy . Carbohydr. Polym. , 2015 . 116 307 .

Y. Liu , Y. Li , H. Chen , G. Yang , X. Zheng , S. Zhou . Carbohydr. Polym , 2014 . 104 101 .

M. Barikani , K.M. Zia , I.A. Bhatti , M. Zuber , H.N. Bhatti . Carbohydr. Polym , 2008 . 74 621 .

R. Sattar , A. Kansar , M. Siddiq . Chinese J. Polym. Sci. , 2015 . 33 ( 9 ): 1313 .

H. Kang , M. Li , Z. Tang , J. Xue , X. Hu , L. Zhang , B. Guo . Mater. Chem , 2014 . 2 7877 .

K. Yu , Y. Liu , J. Leng . RSC Advances , 2014 . 4 2961 .

S. Bai , H. Zou , H.Y. Dietsch , C. Simon , Weder . Macromol. Chem. Phys , 2014 . 215 - 398 . .

F. Xie , L. Huang , Y. Liu , Leng . Polymer , 2014 . 55 5873 .

T.H. Kang , J.M. Lee , W.R. Yu , J.H. Youk , H.W. Ryu . Smart Mater. Struct , 2012 . 21 28 - 35 . .

Xie, T., Polymer, 2011, 52: 4985

K. Du , Z Gan . Mater. Chem., B , 2014 . 2 3340 .

Wong , Y. , J. Kong , L.K. Widjaja , S.S. Venkatraman . Sci. Chin. Chem , 2014 . 57 476 .

J. Shao , Y.L. Liu , S. Xiang , X.C. Bian , J.R. Sun , G. Li , X.S. Chen , H.Q. Hou . Polym. Sci , 2015 . 33 ( 12 ): 1713 .

A. Södergård , Stolt . Prog. Polym. Sci. , 2002 . 27 1123 .

Y. Zhang , S. Liu , X. Wang , Z.Y. Zhang , X.B. Jing , Z.Y. Zhang , X.B. Jing , P. Zhang , Z.G. Xie . Chinese J. Polym. Sci. , 2014 . 32 ( 8 ): 1111 .

X.F. Niu , F. Tian , L.Z. Wang , X.M. Li , G. Zhou , Y.B. Fan . Chinese J. Polym. Sci. , 2014 . 32 ( 1 ): 43 .

J. Xu , J. Song . PNAS , 2010 . 107 7652 .

X.L. Lu , W. Cai , Z. Gao , W.J Tang . Polym. Bull , 2007 . 58 381 .

L. Xue , S. Dai , Z. Li . Macromolecules , 2009 . 42 964 .

G. Li , D. Li , Y. Niu , T. He , K.C. Chen , K. Xu . Biomed. Mater. Res., A , 2014 . 102 685 .

K.M. Zia , M. Zuber , S. Mahboob , T. Sultana , S. Sultana . Carbohydr. Polym. , 2010 . 80 229 .

Y.C. Chung , I.H. Jung , J.W. Choi , B.C. Chun . Polym. Bull. , 2014 . 71 1153 .

Y.C. Chung , H.Y. Kim , J.H. Yu , B.C. Chun . Macromol. Res , 2015 . 23 350 .

A. Mohammadi , M. Barikani , M. Barmar . Polym. Adv. Technol. , 2013 . 24 978 .

Q. Zhao , H.J. Qi , T. Xie . Prog. Polym. Sci , 2015 . 79 40 - 50 . .

K.J. Cha , E. Lih , J. Choi , Y.K. Joung , D.J. Ahn , D.K. Han . Macromol. Biosci , 2014 . 14 667 .

T.C. Boire , M.K Gupta , A.L. Zachman , S.H. Lee , D.A. Balikov , K. Kim , L.M. Bellan , H.J. Sung . Acta Biomater. , 2015 . 24 53 .

P. Rychter , E. Pamula , A. Orchel , U. Posadowska , M. Krok-Borkowicz , A. Kaps , N. Smigiel-Gac , A. Smola , J. Kasperczyk , W. Prochwicz , P. Dobrzynski . Biomed. Mater. Res., A , 2015 . 103 3503 .

M. Saatchi , M. Behl , U. Nochel , A. Lenldlein . Rapid Commun , 2015 . 36 880 .

Z. Wen , T. Zhang , Y. Hui , W. Wang , K. Yang , Q. Zhou , Y. Wang . Mater Chem , 2015 . 3 13435 .

M. Montaz , M. Razavi-Nouri , M. Barikani . Mater. Sci , 2014 . 49 7575 .

Y.P. Cao , Y. Guan , J. Du , Y.X. Peng , P.C.W. Yi , A.S.C Chan . Chinese J. Polym. Sci. , 2003 . 21 ( 1 ): 29 .

Liu , Y.P. , Gall , K. , Dunn , M.L. , McCluskey , P . Mech. Mate , 2004 . 36 929 .

Gunes , I.S. , S.C. , Jana . Nanotechnol. , 2008 . 8 1616 .

Views

Downloads

CSCD

Alert me when the article has been cited

Submit

Tools

Publicity Resources

Thermal, Mechanical and Electrical Studies of Novel Shape Memory Polyurethane/Polyaniline Blends

Two-way Shape Memory Effect of Polycaprolactone-based Polyurethane via Synergistic Role of Hydrogen Bonding and Crystallization Tuned by Malic Acid

Soft-segment-engineered Self-healing Polyurethane for High-performance Electrorheological Elastomers and Capacitive Sensors

Water Swelling-induced Stiffness Enhancement of Polymer Hydrogels

Sliding Dynamics of Ring Chain on a Rod-Coil Block Copolymer in Rotaxane

Related Author

Rabia Sattar

Ayesha Kausar

Muhammad Siddiq

Xue-Qing Li

Shuai Lu

Jun-Jie Tan

Bo Lv

Hong-Ye Yan

Related Institution

Department of Chemistry, Quaid-i-Azam University

Nanosciences and Catalysis Division, National Centre for Physics, Quaid-i-Azam University Campus

School of Chemistry and Chemical Engineering, Wuhan University of Science and Technology

School of Textile Science and Engineering, State Key Laboratory of New Textile Materials and Advanced Processing Technology, Wuhan Textile University

Hubei Key Laboratory of Pollutant Analysis & Reuse Technology, Hubei Normal University

⁰