Preparation of Polystyrene/Triphenyl Phosphate Composites by Suspension Polymerization and Melt Extrusion Method——A Comparative Study

doi:10.1007/s10118-016-1791-7

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Preparation of Polystyrene/Triphenyl Phosphate Composites by Suspension Polymerization and Melt Extrusion Method——A Comparative Study

Papers | Updated：2022-02-21

- Preparation of Polystyrene/Triphenyl Phosphate Composites by Suspension Polymerization and Melt Extrusion Method——A Comparative Study
- Vol. 34, Issue 6, Pages: 688-696(2016)
- Affiliations：
  
  a.National Engineering Research Center of Flame Retardant Materials, School of Materials, Beijing Institute of Technology, Beijing 100081, China
  b.Fire Command Department, Chinese People's Armed Police Forces Academy, Langfang 065000, China
- Author bio：
  
  Xiang-mei Li (李向梅), E-mail: bjlglxm@bit.edu.cn
- Funds：
- DOI：10.1007/s10118-016-1791-7
  CLC：
- Received：26 November 2015，
  
  Revised：2016-1-28，
  
  Accepted：18 February 2016，
  
  Published：2016-06
- Accepted：
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Preparation of Polystyrene/Triphenyl Phosphate Composites by Suspension Polymerization and Melt Extrusion Method——A Comparative Study[J]. 2016, 34(6): 688-696.
DOI：

Preparation of Polystyrene/Triphenyl Phosphate Composites by Suspension Polymerization and Melt Extrusion Method——A Comparative Study[J]. 2016, 34(6): 688-696. DOI： 10.1007/s10118-016-1791-7.

摘要

Abstract

Polystyrene (PS)/triphenyl phosphate (TPP) composites were prepared by both suspension polymerization and melt extrusion

and a comparative study of the flame retardance and mechanical properties was carried out. The results showed that suspension polymerization was a better technique than melt extrusion for obtaining good dispersity of the PS/TPP composite. The TPP nanoparticles

which were approximately 50 nm in size

were homogenously and uniformly dispersed in the PS matrix by suspension polymerization in one-step. However

the PS/TPP composite was partially agglomerated

exhibiting irregularly shaped micron-scale particles as a result of melt extrusion. In contrast to the melt extrusion

the limited oxygen index (LOI) of the PS/TPP nanocomposite by suspension polymerization increased to 22.6% from 21.8%

and time to ignition (TTI) increased by 12.3%

the peak heat release rate (PHRR) decreased by 8.5%

and the total heat release (THR) decreased by 11.0%. The mechanical properties of the PS/TPP nanocomposite by suspension polymerization also increased. The tensile strength

elongation at break

and flexural strength increased by 36.4%

8.5%

and 108%

respectively.

关键词

Keywords

references

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