Diethanol Ammonium-borate Based Polybetaine with Tunable UCST Phase Transition

Shi Mei; Duan Xin-rui; Liu Zhao-tie; Liu Zhong-wen; Jiang Jin-qiang

doi:10.1007/s10118-016-1790-8

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Diethanol Ammonium-borate Based Polybetaine with Tunable UCST Phase Transition

Papers | Updated：2022-02-21

- Diethanol Ammonium-borate Based Polybetaine with Tunable UCST Phase Transition
- Vol. 34, Issue 6, Pages: 777-784(2016)
- Affiliations：
  
  Key Laboratory of Applied Surface and Colloid Chemistry, Ministry of Education, School of Chemistry & Chemical Engineering, Shaanxi Normal University, Xi'an 710062, China
- Author bio：
  
  Jin-qiang Jiang (江金强), E-mail: jiangjq@snnu.edu.cn
- Funds：
  
  the National Natural Science Foundation of China;the Program for Changjiang Scholars and Innovative Research Team in Universities;the Natural Science Basic Research Plan in Shaanxi Province of China;the Program of Introducing Talents of Discipline to Universities;Shaanxi Innovative Research Team for Key Science and Technology;the One Hundred Plan of Shaanxi Province()
- DOI：10.1007/s10118-016-1790-8
  CLC：
- Received：27 December 2015，
  
  Revised：2016-1-26，
  
  Published：2016-06
- Accepted：
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Shi Mei, Duan Xin-rui, Liu Zhao-tie, et al. Diethanol Ammonium-borate Based Polybetaine with Tunable UCST Phase Transition[J]. 2016, 34(6): 777-784.
DOI：

Shi Mei, Duan Xin-rui, Liu Zhao-tie, et al. Diethanol Ammonium-borate Based Polybetaine with Tunable UCST Phase Transition[J]. 2016, 34(6): 777-784. DOI： 10.1007/s10118-016-1790-8.

摘要

Abstract

A betaine-type styrene monomer with the quaternary ammonium-borate anion inner-salt pair was synthesized through the quaternization reaction and polymerized to afford the target polybetaine of poly(4-vinylbenzyl methyl-diethanol ammonium borate) (PVMAB). The chemical structures of the monomer and polymer were well demonstrated with

H-NMR and

B-NMR spectra analysis. The thermal-sensitive experiment showed that PVMAB in water afforded gradually well-defined sigmoidal transmittance-temperature (

) curves along with the increasing polymer concentration. However

the phase transition temperatures at the bottom of the S-shaped curves were always below 10 ℃ due to the very weak zwitterionic association of the ammonium-borate inner-salt pairs. The UCST phase transition could also be tuned by changing the ethanol content in the ethanol/water mixture. And the cytotoxicity experiment demonstrated the good biomimetic property of PVMAB. This study enriches the toolbox of polybetaines by introducing the quaternary ammonium-borate anion zwitterionic pair in the repeat units

therefore broadens the scope of synthetic polybetaines.

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references

A.J. Duncan, , D.J Leo, , T.E. Long, . Macromolecules , 2008 . 41 ( 21 ): 7765 .

J. Ramos, , J Forcada, , R. Hidalgo-Alvarez, . Chem. Rev. , 2014 . 114 ( 1 ): 367 .

J.B. Schlenoff, . Langmuir , 2014 . 30 ( 32 ): 9625 .

A.B Lowe, , C.L. McCormick, . Chem. Rev. , 2002 . 102 ( 11 ): 4177 .

H. Willcock, , A. Lu, , C.F. Hansell, , E. Chapman, , I.R Collins, , R.K. O'Reilly, . Polym. Chem. , 2014 . 5 1023 .

O. Azzaroni, , A.A Brown, , W.T.S. Huck, . Angew. Chem. , 2006 . 118 ( 11 ): 1802 .

W.S. Li, , L.W. Huang, , X.Y. Ying, , Y. Jian, , Y. Hong, , F.Q Hu, , Y.Z. Du, . Angew. Chem. , 2015 . 127 ( 10 ): 3169 .

V.A. Izumrudov, , N.I. Domashenko, , M.V Zhiryakova, , O.V. Davydova, . J. Phys. Chem. B , 2005 . 109 ( 37 ): 17391 .

J. Bohrisch, , T. Schimmel, , H Engelhardt, , W. Jaeger, . Macromolecules , 2002 . 35 ( 10 ): 4143 .

M.C.C Azevedo, , A.M.V. Cavaleiro, . J. Chem. Educ. , 2012 . 89 ( 6 ): 767 .

G. Cruz, . J. Chem. Educ. , 2013 . 90 ( 12 ): 1645 .

R. Pelton, , Z. Hu, , H Ketelson, , D. Meadows, . Langmuir , 2009 . 25 ( 1 ): 192 .

J. Shim, , D.G. Kim, , H.J. Kim, , J.H Lee, , J.C. Lee, . ACS Appl. Mater. Inter. , 2015 . 7 ( 14 ): 7690 .

H Steinberg, , D.L. Hunter, . Ind. Eng. Chem. , 1957 . 49 ( 2 ): 174 .

G.Q. Shen, , Z. Zheng, , Y. Wan, , X.D. Xu, , L.L. Cao, , Q.X. Yue, , T.J Sun, , A.R. Liu, . Wear , 2000 . 246 55 .

D.W Tanner, , T.C. Bruice, . J. Am. Chem. Soc. , 1967 . 89 ( 26 ): 6954 .

J. Nizioł, , Z. Zieliński, , A. Leś, , M. Dąbrowska, , W Rode, , T. Ruman, . Bioorgan. Med. Chem. , 2014 . 22 ( 15 ): 3906 .

D.J. Kim, , S.D. Mun, , S. Yoon, , C.H. Oh, , H.R. Park, , T.S. You, , J Lee, , Y. Kim, . Polyhedron , 2011 . 30 ( 6 ): 1076 .

T. Qi, , A. Sonoda, , Y. Makita, , H. Kanoh, , K Ooi, , T. Hirotsu, . Ind. Eng. Chem. Res. , 2002 . 41 ( 2 ): 133 .

Z.Y. Liang, , L.J. Ma, , C.X Lu, , Y.J. Zhai, . J. Surfactants Deterg. , 2012 . 15 ( 2 ): 217 .

Y. Miyazaki, , K. Yoshimura, , Y. Miura, , H Sakashita, , K. Ishimaru, . Polyhedron , 2003 . 22 ( 6 ): 909 .

G. Taler, , A Schejter, , G. Navon, . Inorg. Chim. Acta , 1998 . 273 388 .

Y. Miyazaki, , T. Fujimori, , H. Okita, , T Hirano, , K. Yoshimura, . Dalton Trans. , 2013 . 42 ( 29 ): 10473 .

Q.L Zhang, , R. Hoogenboom, . Prog. Polym. Sci. , 2015 . 48 122 .

S.Y. Noskov, , G Lamoureux, , B. Roux, . J. Phys. Chem. B , 2005 . 109 ( 14 ): 6705 .

P. Bustamante, , J. Navarro, , S Romero, , B. Escalera, . J. Pharm. Sci. , 2002 . 91 ( 3 ): 874 .

R. Hoogenboom, , S. Rogers, , A. Can, , C.R. Becer, , C. Guerrero-Sanchez, , D. Wouters, , S Hoeppener, , U.S. Schubert, . Chem. Commun. , 2009 . 37 5582 .

B.R. Twaites, , C.H. Alarcón, , M. Lavigne, , A. Saulnier, , S.S. Pennadam, , D. Cunliffe, , D.C Górecki, , C. Alexander, . J. Control. Release , 2005 . 108 472 .

M. Tian, , R.D. Cheng, , J. Zhang, , Z.T. Liu, , Z.W Liu, , J.Q. Jiang, . Langmuir , 2016 . 32 ( 1 ): 12 .

C.Z. Geng, , X. Hu, , G.H. Yang, , Q. Zhang, , F Chen, , Q. Fu, . Chinese J. Polym. Sci. , 2015 . 33 ( 1 ): 61 .

Y. Hu, , L. Gan, , Q.X. Li, , H. Tao, , L. Ye, , A.Y Zhang, , Z.G. Feng, . Chinese J. Polym. Sci. , 2014 . 32 ( 12 ): 1717 .

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