Improving Ferro-and Piezo-Electric Properties of Hydrogenized Poly(vinylidene fluoride-trifluoroethylene) Films by Annealing at Elevated Temperatures

Wang Jian; Zhong Li; Yuan Yan; Xiao Wang; Yun-chuan Xie; Zhi-cheng Zhang

doi:10.1007/s10118-016-1782-8

Your Location：

Home >

Browse articles >

Improving Ferro-and Piezo-Electric Properties of Hydrogenized Poly(vinylidene fluoride-trifluoroethylene) Films by Annealing at Elevated Temperatures

PAPERS | Updated：2021-05-12

- Improving Ferro-and Piezo-Electric Properties of Hydrogenized Poly(vinylidene fluoride-trifluoroethylene) Films by Annealing at Elevated Temperatures
- Chinese Journal of Polymer Science Vol. 34, Issue 5, Pages: 649-658(2016)
- Affiliations：
  
  a.Department of Applied Chemistry, MOE Key Laboratory for Nonequilibrium Synthesis and Modulation of Condensed Matter, School of Science, Xi'an Jiaotong University, Xi'an 710049, China
  b.College of Material Science and Engineering, Xi'an University of Science and Technology, Xi'an 710054, China
  c.School of Electronic and Information Engineering, Xi'an Jiaotong University, Xi'an 710049, China
- Author bio：
  
  Yun-chuan Xie (解云川), E-mail: ycxie@mail.xjtu.edu.cn
  Zhi-cheng Zhang (张志成), E-mail: zhichengzhang@mail.xjtu.edu.cn
- Funds：
- DOI：10.1007/s10118-016-1782-8
  CLC：
- Received：27 November 2015，
  
  Revised：2016-1-4，
  
  Accepted：04 January 2016，
  
  Published：2016-05
- Accepted：
Scan QR Code
Wang Jian, Zhong Li, Yuan Yan, et al. Improving Ferro-and Piezo-Electric Properties of Hydrogenized Poly(vinylidene fluoride-trifluoroethylene) Films by Annealing at Elevated Temperatures[J]. Chinese Journal of Polymer Science, 2016, 34(5): 649-658.
DOI：

Wang Jian, Zhong Li, Yuan Yan, et al. Improving Ferro-and Piezo-Electric Properties of Hydrogenized Poly(vinylidene fluoride-trifluoroethylene) Films by Annealing at Elevated Temperatures[J]. Chinese Journal of Polymer Science, 2016, 34(5): 649-658. DOI： 10.1007/s10118-016-1782-8.

摘要

Abstract

After annealing the solution cast P(VDF-TrFE) films at elevated temperatures

which were synthesized

via

a full hydrogenation process from P(VDF-CTFE) with a composition of VDF/TrFE=80/20 (mol%)

a series of P(VDF-TrFE) films were fabricated in present work. The crystalline and ferroelectric phases of the films were carefully characterized and their dielectric

ferroelectric and piezoelectric properties were systematically investigated. The improved crystalline and ferroelectric phases in the films induced by annealing at elevated temperatures are responsible for the significant improved electric properties of the films. The optimized annealing temperature is found to be 130 ℃ and the best performance including the highest dielectric constant of 12.5 at 1 kHz

the largest maximum polarization of 11.21 μC/cm

and remnant polarization of 7.22 μC/cm

the lowest coercive electric field of 56 MV/m

and the highest piezoelectric coefficient of-25 pC/N is observed.

关键词

Keywords

references

H. Kawai . Jpn. J. Appl. Phys. , 1969 . 8 975 DOI: 10.1143/JJAP.8.975 http://doi.org/10.1143/JJAP.8.975 .

A.J. Lovinger . Jpn. J. Appl. Phys. , 1985 . 24 18 .

J.M. Herbert , A.M. Glass , T.T. Wang . "The application of ferroelectric polymers" , : New York Chapman & Hall , 1988 .

H.S. Nalwa , polymers" "Ferroelectric , York New . : New York Marcel Dekker , "Ferroelectric polymers" , 1995 .

S.J. Kang , Y.J. Park , J. Hwang , H.J. Jeong , J.S. Lee , K.J. Kim , K.C. Kim , J. Huh , C. Park . Adv. Mater. , 2007 . 19 581 DOI: 10.1002/(ISSN)1521-4095 http://doi.org/10.1002/(ISSN)1521-4095 .

J.S. Lee , A.A. Prabu , Y.M. Chang , K.J. Kim . Macromol. Symp. , 2007 . 13 249 .

R.C.G. Naber , C. Tanase , P.W.M. Blom , G.H. Gelinck , Marsman , W. A , F.J. Touwslager , S. Setayesh , D.M.D. Leeuw . Nat. Mater. , 2005 . 4 243 DOI: 10.1038/nmat1329 http://doi.org/10.1038/nmat1329 .

E. Fukada . Ferroelectrics , 1995 . 171 1 DOI: 10.1080/00150199508018415 http://doi.org/10.1080/00150199508018415 .

D.R. Dillon , K.K. Tenneti , C.Y. Li , F.K. Ko , I. Sics , B.S. Hsiao . Polymer , 2006 . 47 1678 DOI: 10.1016/j.polymer.2006.01.015 http://doi.org/10.1016/j.polymer.2006.01.015 .

A.J. Lovinger . Polymer , 1981 . 22 412 DOI: 10.1016/0032-3861(81)90058-6 http://doi.org/10.1016/0032-3861(81)90058-6 .

K.C. Satyanarayana , K. Bolton . Polymer , 2012 . 53 2927 DOI: 10.1016/j.polymer.2012.04.008 http://doi.org/10.1016/j.polymer.2012.04.008 .

G.T. Davis , M.G. Broadhurst , A.J. Lovinger , T. Furukawa . Ferroelectrics , 1984 . 57 73 DOI: 10.1080/00150198408012753 http://doi.org/10.1080/00150198408012753 .

A.J. Lovinger , G.E. Johnson , H.E. Bair , E.W. Anderson . J. Appl. Phys. , 1984 . 56 2412 DOI: 10.1063/1.334303 http://doi.org/10.1063/1.334303 .

T. Yagi , M. Tatemoto . Polym. J. , 1979 . 11 429 DOI: 10.1295/polymj.11.429 http://doi.org/10.1295/polymj.11.429 .

H. Ohigashi , K. Omote , T. Gomyo . Appl. Phys. Lett. , 1995 . 66 3281 DOI: 10.1063/1.113730 http://doi.org/10.1063/1.113730 .

T. Yagi , M. Tatemoto , J. Sako . Polym. J. , 1980 . 12 209 DOI: 10.1295/polymj.12.209 http://doi.org/10.1295/polymj.12.209 .

T. Furukawa , G.E. Johnson , H.E. Bair , Y. Tajitsu , A. Chiba , E. Furukawa . Ferroelectrics , 1981 . 32 61 DOI: 10.1080/00150198108238674 http://doi.org/10.1080/00150198108238674 .

K. Tashiro , H. Tadokoro , M. Kobayashi . Ferroelectrics , 1981 . 32 167 DOI: 10.1080/00150198108238688 http://doi.org/10.1080/00150198108238688 .

K. Aimi , S. Ando , P. Avalle , R.K. Harris . Polymer , 2004 . 45 2281 DOI: 10.1016/j.polymer.2004.01.005 http://doi.org/10.1016/j.polymer.2004.01.005 .

H. Ohigashi , N. Kagami , G.R. Li . J. Appl. Phys. , 1992 . 71 506 DOI: 10.1063/1.350686 http://doi.org/10.1063/1.350686 .

L. Ibos , A. Bernès , C. Lacabanne . J. Ferroelectrics , 2015 . 320 15 .

J.H. Kim , D.Y. Khang . Eur. Polym. J. , 2014 . 59 78 DOI: 10.1016/j.eurpolymj.2014.07.017 http://doi.org/10.1016/j.eurpolymj.2014.07.017 .

M.H.M. Wahid , S.Z. Sa'ad , M.N. Sarip , W.C. Gan , Majid. W.H. Abd. . J. Adv. Mater. Res. , 2013 . 812 60 DOI: 10.4028/www.scientific.net/AMR.812 http://doi.org/10.4028/www.scientific.net/AMR.812 .

Y.Y. Lu , J. Claude , B. Neese , Q.M. Zhang , Q. Wang . J. Am. Chem. Soc. , 2006 . 128 8120 DOI: 10.1021/ja062306x http://doi.org/10.1021/ja062306x .

G. Moggi , P. Bonardelli , Polym. Sci. J. . Part B: Polym. Phys. , 1984 . 22 357 .

S.B. Tan , J.J. Li , Z.C. Zhang . Macromolecules , 2011 . 44 7911 DOI: 10.1021/ma201942z http://doi.org/10.1021/ma201942z .

E.Q. Liu , Z.C. Zhang . Acta Polymerica Sinica (in Chinese) , 2010 . ( 8 ): 1087 .

S.B. Tan , E.Q. Liu , Q.P. Zhang , Z.C. Zhang . Chem. Commun. , 2011 . 47 4544 DOI: 10.1039/c1cc00106j http://doi.org/10.1039/c1cc00106j .

Y.Y. Lu , J. Claude , Q.M. Zhang , Q. Wang . Macromolecules , 2006 . 39 6962 DOI: 10.1021/ma061311i http://doi.org/10.1021/ma061311i .

Z.M. Wang , Z.C. Zhang , T.C.M. Chung . Macromolecules , 2006 . 39 4268 DOI: 10.1021/ma060738m http://doi.org/10.1021/ma060738m .

Z.C. Zhang , Q.J. Meng , T.C.M. Chung . Polymer , 2009 . 50 707 DOI: 10.1016/j.polymer.2008.11.005 http://doi.org/10.1016/j.polymer.2008.11.005 .

W.M. Xia , Z. Xu , Z.C. Zhang , H.Y. Li . Polymer , 2013 . 54 440 DOI: 10.1016/j.polymer.2012.11.027 http://doi.org/10.1016/j.polymer.2012.11.027 .

Q.P. Zhang , W.M. Xia , Z.G. Zhu , Z.C. Zhang . J. Appl. Polym. Sci. , 2013 . 217 2094 .

V. Sencadas , S. Lanceros-Mendez , R.S.I. Serra , A.A. Balado , J.L.G. Ribelles . Eur. Phys. J.E. , 2012 . 85 41 DOI: 10.1140/epjb/e2011-20811-8 http://doi.org/10.1140/epjb/e2011-20811-8 .

Views

Downloads

CSCD

Alert me when the article has been cited

Submit

Tools

Publicity Resources

Preparation of Cyclic Olefin Copolymers with High Glass-transition Temperature via Ethylene/Dicyclopentadiene Copolymerization and Subsequent Hydrogenation

Viscoelastic Property Evolution of Thermoplastic Polyurethane During Annealing Treatment and Its Correlation with Segmental Crystallization

The Effect of Substrate on the Properties of Non-volatile Ferroelectric P(VDF-TrFE)/P3HT Memory Devices

Silk Sericin-inspired Poly-β-homoserine for Protein Protection

Optically Active Helical Poly(phenyl isocyanide)s Bearing Achiral Benzanilide Pendants: from Controlled Synthesis to Enantioseparation Application

Related Author

Bao-Li Wang

Chun-Ji Wu

Pan He

Ling-Yan Huang

Shu-Nan Zhang

Yan-Bo Zhu

Jian-Wen Shan

Ling-Ling Ni

Related Institution

School of Material Science and Engineering, Changchun University of Science and Technology

School of Chemistry and Environmental Engineering, Changchun University of Science and Technology

School of Applied Chemistry and Engineering, University of Science and Technology of China

State Key Laboratory of Polymer Science and Technology, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences

Department of Polymer Science and Engineering, Zhejiang University

⁰