

FOLLOWUS
Department of Chemistry, School of Sciences, Tianjin University, and Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin 300354, China
Yu Chen (陈宇), E-mail: chenyu@tju.edu.cn
Received:10 November 2015,
Revised:2016-1-3,
Accepted:03 January 2016,
Published:2016-05
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Hua-ji Liu, Yue-yue Xu, Yu Chen. Influence of Sodium Dodecyl Sulfate on the Phase Transition of Thermoresponsive Hyperbranched Polymer in Water[J]. Chinese Journal of Polymer Science, 2016, 34(5): 585-593.
Hua-ji Liu, Yue-yue Xu, Yu Chen. Influence of Sodium Dodecyl Sulfate on the Phase Transition of Thermoresponsive Hyperbranched Polymer in Water[J]. Chinese Journal of Polymer Science, 2016, 34(5): 585-593. DOI: 10.1007/s10118-016-1779-3.
The influence of sodium dodecyl sulfate (SDS) on the cloud point temperature (
T
cp
) of the aqueous solution of thermoresponsive hyperbranched polyethylenimine derivative HPEI-IBAm was studied systematically. When pH was below 8.5
HPEI-IBAm was positively-charged. Initially
the
T
cp
of HPEI-IBAm decreased significantly
followed by an obvious increase with the increase of SDS concentration. The lower the pH was
the higher the SDS concentration was required to achieve the minimum
T
cp
. When pH was above 8.5
HPEI-IBAm was neutral and raising the SDS concentration led to the gradual increase of
T
cp
. Compared to linear poly(
N
-isopropyl acrylamide) (PNIPAm)
the
T
cp
of the current hyperbranched HPEI-IBAm was more sensitive to SDS. The thermoresponsive HPEI-IBAm/SDS complex was used as host to accommodate the non-polar pyrene in water. The lowest SDS concentration for effectively enhancing the solubility of pyrene in water was around 6.4 mmol·L
-1
. When HPEI-IBAm was present
the SDS concentration threshhold was decreased to about 0.31 mmol·L
-1
. Fluorescence technique with pyrene as the hydrophobic probe demonstrated that the SDS concentration of 7.2 mmol·L
-1
was required to form the hydrophobic domain to accommodate pyrene guests without HPEI-IBAm
while only 0.2 mmol·L
-1
of SDS was required in the presence of HPEI-IBAm.
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