Thermal Stability and Thermal Aging of Poly(vinyl chloride)/MgAl Layered Double Hydroxides Composites

Hong-mei Zhang; Shu-hua Zhang; Polite Stewart; Chen-hui Zhu; Wei-jun Liu; Alexander Hexemer; Eric Schaible; Cheng Wang

doi:10.1007/s10118-016-1778-4

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Thermal Stability and Thermal Aging of Poly(vinyl chloride)/MgAl Layered Double Hydroxides Composites

PAPERS | Updated：2021-05-12

- Thermal Stability and Thermal Aging of Poly(vinyl chloride)/MgAl Layered Double Hydroxides Composites
- Chinese Journal of Polymer Science Vol. 34, Issue 5, Pages: 542-551(2016)
- Affiliations：
  
  a.College of Chemistry and Chemical Engineering, Shanghai University of Engineering Science, Shanghai 201620, China
  b.Advanced Light Source, Lawrence Berkeley National Laboratory, Berkeley 94720, USA
  c.College of Mechanical Engineering, Shanghai University of Engineering Science, Shanghai 201620, China
- Author bio：
  
  Shu-hua Zhang (张书华), E-mail: zhangsh@sues.edu.cn
  Cheng Wang (王成), E-mail: cwang2@lbl.gov
- Funds：
- DOI：10.1007/s10118-016-1778-4
  CLC：
- Received：28 October 2015，
  
  Revised：2015-11-30，
  
  Accepted：27 December 2015，
  
  Published：2016-05
- Accepted：
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Hong-mei Zhang, Shu-hua Zhang, Polite Stewart, et al. Thermal Stability and Thermal Aging of Poly(vinyl chloride)/MgAl Layered Double Hydroxides Composites[J]. Chinese Journal of Polymer Science, 2016, 34(5): 542-551.
DOI：

Hong-mei Zhang, Shu-hua Zhang, Polite Stewart, et al. Thermal Stability and Thermal Aging of Poly(vinyl chloride)/MgAl Layered Double Hydroxides Composites[J]. Chinese Journal of Polymer Science, 2016, 34(5): 542-551. DOI： 10.1007/s10118-016-1778-4.

摘要

Abstract

MgAl-LDH (layered double hydroxides) were prepared with CO(NH

)

Cl and NH

·H

O by the co-precipitation method

respectively. Corresponding composite membranes were prepared by the coating method. LDHs were characterized by WAXS

-TPD and SEM. The morphology of the PVC/LDHs composite membranes were characterized by means of SEM. The thermal stability of the membranes was analyzed by air aging box and TGA-FTIR. The SEM results show that nano-particles can be compatible with poly(vinyl chloride) (PVC) matrix homogeneously by the stirring-ultrasound blend method with two steps. Furthermore

the air aging box results proved that MgAl-CO(NH

)

-LDH has the best effect on thermal stability of PVC. TGA-FTIR results show that MgAl-CO(NH

)

-LDH could adsorb more HCl that resulted from the degradation of PVC and improve the pyrolysis temperature of the first degradation stage by 15 K compared with PVC.

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references

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