Novel Terpolymers of Poly(<italic style="font-style: italic">p</italic>-dioxanone-<italic style="font-style: italic">co</italic>-trimethylene carbonate-<italic style="font-style: italic">co</italic>-L-phenylalanine): Synthesis, Characterization, Thermal Properties and Copolymerization Mechanism

Li-nan Li; Cheng-dong Xiong; Dong-liang Chen

doi:10.1007/s10118-016-1777-5

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Novel Terpolymers of Poly(p-dioxanone-co-trimethylene carbonate-co-L-phenylalanine): Synthesis, Characterization, Thermal Properties and Copolymerization Mechanism

PAPERS | Updated：2021-05-12

- Novel Terpolymers of Poly(p-dioxanone-co-trimethylene carbonate-co-L-phenylalanine): Synthesis, Characterization, Thermal Properties and Copolymerization Mechanism
- Chinese Journal of Polymer Science Vol. 34, Issue 5, Pages: 594-605(2016)
- Affiliations：
  
  a.Chengdu Institute of Organic Chemistry, Chinese Academy of Sciences, Chengdu 610041, China
  b.University of Chinese Academy of Sciences, Beijing 100049, China
- Author bio：
  
  Dong-liang Chen (陈栋梁), E-mail: 1633cdl@cioc.ac.cn
- Funds：
- DOI：10.1007/s10118-016-1777-5
  CLC：
- Received：11 November 2015，
  
  Revised：2015-12-26，
  
  Accepted：26 December 2015，
  
  Published：2016-05
- Accepted：
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Li-nan Li, Cheng-dong Xiong, Dong-liang Chen. Novel Terpolymers of Poly(p-dioxanone-co-trimethylene carbonate-co-L-phenylalanine): Synthesis, Characterization, Thermal Properties and Copolymerization Mechanism[J]. Chinese Journal of Polymer Science, 2016, 34(5): 594-605. DOI: 10.1007/s10118-016-1777-5.
DOI：

Li-nan Li, Cheng-dong Xiong, Dong-liang Chen. Novel Terpolymers of Poly(p-dioxanone-co-trimethylene carbonate-co-L-phenylalanine): Synthesis, Characterization, Thermal Properties and Copolymerization Mechanism[J]. Chinese Journal of Polymer Science, 2016, 34(5): 594-605. DOI: 10.1007/s10118-016-1777-5. DOI：

摘要

Abstract

In order to exploit the biological functions of materials

a series of new random terpolymers were synthesized by the ring-opening polymerization of

-dioxanone

trimethylene carbonate

and L-phenylalanine

-carboxyanhydride (L-Phe-NCA) in the presence of stannous octoate. The terpolymers were characterized by

H-NMR

C-NMR

FTIR

and gel permeation chromatography. The effects of the reactant ratio

catalyst dosage

reaction temperature and time on the copolymerization were investigated

and were found to regulate the composition of the terpolymer. Increases in the reaction temperature

polymerization time

L-Phe-NCA monomer amount

and catalyst content generated a product with a slightly decreased molecular weight. The crystallinity of the terpolymer was investigated by differential scanning calorimetry and polarized optical microscopy. A reasonable mechanism for the polymerization was proposed based on the obtained results.

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references

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Novel Terpolymers of Poly(p-dioxanone-co-trimethylene carbonate-co-L-phenylalanine): Synthesis, Characterization, Thermal Properties and Copolymerization Mechanism

DOI：10.1007/s10118-016-1777-5

摘要

Abstract

关键词

Keywords

references