Novel Poly(methyl methacrylate)-based Ionomers Used as Multifunctional Aids to Modify Poly(vinyl chloride)

Li-na Zhang; Yi-hu Song; Qiang Zheng

doi:10.1007/s10118-016-1775-7

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Novel Poly(methyl methacrylate)-based Ionomers Used as Multifunctional Aids to Modify Poly(vinyl chloride)

Updated：2021-06-21

- Novel Poly(methyl methacrylate)-based Ionomers Used as Multifunctional Aids to Modify Poly(vinyl chloride)
- Chinese Journal of Polymer Science Vol. 34, Issue 4, Pages: 483-490(2016)
- Affiliations：
  
  a.Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027, China
  b.MOE Key Laboratory of Macromolecular Synthesis and Functionalization, Zhejiang University, Hangzhou 310027, China
- Author bio：
  
  *Yi-hu Song (宋义虎), E-mail: s_yh0411@zju.edu.cn
  Qiang Zheng (郑强), E-mail: zhengqiang@zju.edu.cn
- Funds：
- DOI：10.1007/s10118-016-1775-7
  CLC：
- Received：26 October 2015，
  
  Revised：2015-12-13，
  
  Accepted：16 December 2015，
  
  Published：2016-04
- Accepted：
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Li-na Zhang, Yi-hu Song, Qiang Zheng. Novel Poly(methyl methacrylate)-based Ionomers Used as Multifunctional Aids to Modify Poly(vinyl chloride)[J]. Chinese Journal of Polymer Science, 2016, 34(4): 483-490.
DOI：

Li-na Zhang, Yi-hu Song, Qiang Zheng. Novel Poly(methyl methacrylate)-based Ionomers Used as Multifunctional Aids to Modify Poly(vinyl chloride)[J]. Chinese Journal of Polymer Science, 2016, 34(4): 483-490. DOI： 10.1007/s10118-016-1775-7.

摘要

Abstract

Poly(methyl methacrylate) (PMMA) based ionomers with different lanthanum (La(III)) contents (PMMA-XLa) synthesized by free radical solution polymerization were applied to poly(vinyl chloride) (PVC) resins as a kind of multifunctional aids

and their performances were evaluated by measuring the static stability time

initial discoloration

transparency

fusion behavior and tensile strength of the modified PVC. The ionomers with proper lanthanum (La(III)) contents show a better thermal stability efficiency in comparison with traditional stabilizer lanthanum stearate. Meantime

they can accelerate PVC plasticization more efficiently than PMMA. The rigid PVC products stabilized with the ionomers present good transparency and enhanced tensile strength.

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