Linear Viscoelastic Behaviors of Polybutene-1 Melts with Various Structure Parameters
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Linear Viscoelastic Behaviors of Polybutene-1 Melts with Various Structure Parameters
Chinese Journal of Polymer ScienceVol. 34, Issue 2, Pages: 174-184(2016)
Affiliations:
a.Shandong Provincial Key Laboratory of Olefin Catalysis and Polymerization, Key Laboratory of Rubber-Plastics (Ministry of Education), Qingdao University of Science and Technology, Qingdao 266042, China
b.Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Engineering Plastics, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
Author bio:
**Ai-hua He (贺爱华), E-mail: aihuahe@iccas.ac.cn or ahhe@qust.edu.cn
Hua-feng Shao, Shu-lei Wang, Xia Dong, et al. Linear Viscoelastic Behaviors of Polybutene-1 Melts with Various Structure Parameters[J]. Chinese Journal of Polymer Science, 2016, 34(2): 174-184.
DOI:
Hua-feng Shao, Shu-lei Wang, Xia Dong, et al. Linear Viscoelastic Behaviors of Polybutene-1 Melts with Various Structure Parameters[J]. Chinese Journal of Polymer Science, 2016, 34(2): 174-184.DOI: 10.1007/s10118-016-1736-1.
Linear Viscoelastic Behaviors of Polybutene-1 Melts with Various Structure Parameters
and isotacticity on the linear viscoelastic behavior of polybutene-1 melts are studied. It is observed that the linear viscoelastic region becomes slightly narrower with increasing frequency. In frequency sweeps
the transition of the polymer melts flow from Newtonian flow to power-law flow can be observed. The melts with higher
M
w
and/or broader MWD
as well as higher isotacticity exhibit higher complex viscosity
zero shear viscosity
viscoelasticity moduli
relaxation modulus
broader transition zone
while lower critical shear rate
non-Newtonian index
and the frequency at which elasticity begins to play an important role. The relationship of zero shear viscosity on
M
w
has been established
which agrees with the classical power law. Furthermore
it is found that the cross-over frequency decreases with increasing
M
w
and the cross-over modulus increases with narrowing MWD.
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