Nickel(II) <italic style="font-style: italic">α</italic>-Diimine Catalysts with Carboxyl Groups for Ethylene Oligomerization and Polymerization

Bing Liu; Meng-zhe Fang; Su-yun Jie; Zhi-yang Bu; Bo-Geng Li

doi:10.1007/s10118-016-1734-3

Your Location：

Home >

Browse articles >

Nickel(II) α-Diimine Catalysts with Carboxyl Groups for Ethylene Oligomerization and Polymerization

Updated：2021-06-21

- Nickel(II) α-Diimine Catalysts with Carboxyl Groups for Ethylene Oligomerization and Polymerization
- Chinese Journal of Polymer Science Vol. 34, Issue 2, Pages: 221-228(2016)
- Affiliations：
  
  State Key Laboratory of Chemical Engineering, College of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, China
- Author bio：
  
  **Su-yun Jie (介素云), E-mail: jiesy@zju.edu.cn
- Funds：
- DOI：10.1007/s10118-016-1734-3
  CLC：
- Received：14 August 2015，
  
  Revised：2015-09-09，
  
  Accepted：21 September 2015，
  
  Published：2016-02
- Accepted：
Scan QR Code
Bing Liu, Meng-zhe Fang, Su-yun Jie, et al. Nickel(II) α-Diimine Catalysts with Carboxyl Groups for Ethylene Oligomerization and Polymerization[J]. Chinese Journal of Polymer Science, 2016, 34(2): 221-228. DOI: 10.1007/s10118-016-1734-3.
DOI：

Bing Liu, Meng-zhe Fang, Su-yun Jie, et al. Nickel(II) α-Diimine Catalysts with Carboxyl Groups for Ethylene Oligomerization and Polymerization[J]. Chinese Journal of Polymer Science, 2016, 34(2): 221-228. DOI: 10.1007/s10118-016-1734-3. DOI：

摘要

Abstract

A series of nickel(II)

-diimine complexes with strong electron-withdrawing carboxyl groups

having reactive hydrogen atoms

were prepared and used as precatalysts for ethylene oligomerization and/or polymerization. The influence of metal halides and ligand structure on the catalytic activity and properties of products was investigated. The results showed that nickel bromide was much more active than nickel chloride

and the substituents at the

ortho

-position of aryl ring had large influence on the properties of products. Therefore

the products ranging from liquid oligomers to polymers could be readily obtained by the variation of the substituents on the ligands and reaction conditions.

关键词

Keywords

references

Views

Downloads

CSCD

Alert me when the article has been cited

Submit

Tools

Publicity Resources

Iminopyridine Manganese and Nickel Complexes: Synthesis, Characterization and Behavior in the Polymerization of 1,3-Butadiene

Access to High-Molecular-Weight Polyethylenes through High Temperature Ethylene Polymerization Catalysed by Ethylene-Bridged ansa-(3-R-Cyclopentadienyl)(Fluorenyl) Zirconocene Complexes

A Phenol-containing α-Diimine Ligand for Nickel- and Palladium-Catalyzed Ethylene Polymerization

Special Topic: Chirality in Polymers

From Molecular Defect to Macroscopic Performance: Manipulating Dichroism and Mechanics in Iodine-doped Poly(vinyl alcohol) via Ethylene Incorporation

Related Author

Giovanni Ricci

Benedetta Palucci

Simona Losio

Anna Sommazzi

Francesco Masi

Guido Pampaloni

Massimo Guelfi

Giovanni Ricci

Related Institution

Centro per l'Integrazione della Strumentazione Scientifica dell'Università di Pisa (C.I.S.U.P.), Università di Pisa,- Pisa

Università di Pisa, Dipartimento di Chimica e Chimica Industriale, Via Moruzzi 13,- Pisa

Scientific Advisor, Via E. Fiumalbi 29, I- Pontedera (PI)

Scientific Advisor, Via Galvani 7,- Sant’Angelo Lodigiano (LO)

Scientific Advisor, Viale Giovanni XXIII 34,- Novara

⁰

Nickel(II) α-Diimine Catalysts with Carboxyl Groups for Ethylene Oligomerization and Polymerization

DOI：10.1007/s10118-016-1734-3

摘要

Abstract

关键词

Keywords

references