Coral-shaped and Core-Shell Structure Copolyethylene Nanocomposites Particles Prepared by <italic style="font-style: italic">in situ</italic> Coordination Polymerization

Jing Wang; Hong-ming Li; Jiang-ping Guo; Qi-gu Huang; Jian-jun Yi; Yun-fang Liu; Ke-jing Gao; Wan-tai Yang

doi:10.1007/s10118-015-1719-7

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Coral-shaped and Core-Shell Structure Copolyethylene Nanocomposites Particles Prepared by in situ Coordination Polymerization

PAPER | Updated：2021-06-21

- Coral-shaped and Core-Shell Structure Copolyethylene Nanocomposites Particles Prepared by in situ Coordination Polymerization
- Chinese Journal of Polymer Science Vol. 33, Issue 12, Pages: 1650-1660(2015)
- Affiliations：
  
  a.State Key Laboratory of Chemical Resource Engineering, Key Laboratory of Carbon Fiber and Functional Polymers, Ministry of Education, Beijing University of Chemical Technology, Beijing 100029, China
  b.Lab for Synthetic Resin Research Institution of Petrochemical Technology, China National Petroleum Corporation, Beijing 100083, China
- Author bio：
  
  **Qi-gu Huang (黄启谷), E-mail: huangqg@mail.buct.edu.cn
- Funds：
- DOI：10.1007/s10118-015-1719-7
  CLC：
- Received：05 May 2015，
  
  Revised：2015-08-05，
  
  Accepted：19 August 2015，
  
  Published：2015-12
- Accepted：
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Jing Wang, Hong-ming Li, Jiang-ping Guo, et al. Coral-shaped and Core-Shell Structure Copolyethylene Nanocomposites Particles Prepared by in situ Coordination Polymerization[J]. Chinese Journal of Polymer Science, 2015, 33(12): 1650-1660. DOI: 10.1007/s10118-015-1719-7.
DOI：

Jing Wang, Hong-ming Li, Jiang-ping Guo, et al. Coral-shaped and Core-Shell Structure Copolyethylene Nanocomposites Particles Prepared by in situ Coordination Polymerization[J]. Chinese Journal of Polymer Science, 2015, 33(12): 1650-1660. DOI: 10.1007/s10118-015-1719-7. DOI：

摘要

Abstract

The example of the preparation of nano- and micro-scaled

coral-shaped and core-shell topological morphology of copolyethylene particles promoted by the novel heterogeneous non-metallocene catalyst (

-CH

PhO)TiCl

/carbon nanotubes (CNTs) was reported. Mass fraction of titanium component of the catalyst was 4.0 wt% determined by ICP analysis. The catalyst system can effectively catalyze polymerization of ethylene and copolymerization of ethylene with 1-hexene. Morphological examination of the obtained polymer particles was carried out by scanning electron microscope (SEM) and high resolution transmission electron microscope (HR-TEM) technique. The results revealed that the morphology of the nascent copolyethylene particles looked like coral shape with size in micro-scaled and featured the core-shell structure consisting of CNTs as the core and copolyethylene as the shell.

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Coral-shaped and Core-Shell Structure Copolyethylene Nanocomposites Particles Prepared by in situ Coordination Polymerization

DOI：10.1007/s10118-015-1719-7

摘要

Abstract

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Keywords

references