Wen-bo Jiang, Yong-yun Ji, Wen-chang Lang, et al. Surface-induced Morphologies of ABC Star Triblock Copolymer in Spherical Cavities[J]. Chinese Journal of Polymer Science, 2015, 33(11): 1503-1515.
DOI:
Wen-bo Jiang, Yong-yun Ji, Wen-chang Lang, et al. Surface-induced Morphologies of ABC Star Triblock Copolymer in Spherical Cavities[J]. Chinese Journal of Polymer Science, 2015, 33(11): 1503-1515.DOI: 10.1007/s10118-015-1706-z.
Surface-induced Morphologies of ABC Star Triblock Copolymer in Spherical Cavities
The morphologies and phase diagrams exhibited by symmetric ABC star triblock copolymer nanoparticles are investigated on the basis of real-space self-consistent field theory. The ABC star triblock copolymers were chosen to be tiling-forming with fixed polymer parameter and the spherical boundaries were modeled using the masking technique. We first study a number of examples where the ABC triblock copolymers confined in spherical cavities with neutral surface. Then
two types of spherical cavity distinct preferential surfaces are considered
including both A-block attractive and repulsive preferential surfaces. We aim at the effects due to various spherical cavity diameters and the degree of interactions between the polymer and the spherical surface. A variety of morphologies
such as ring-like structures
concentric sphere
and irregular cylinder
were identified in phase diagrams. The results show that both the degree of interactions and spherical diameters can influence the formation of morphologies so that ring-like structures and other novel structures could be obtained.
关键词
Keywords
references
The trial reading is over, you can activate your VIP account to continue reading.
Regulating Intermolecular Interactions through Phenyl-alkyl Side-chain Engineering for High-efficiency Organic Solar Cells
Compatibilizer-aided Fabrication of a 'High-entropy Polymer Blend'
Influence of the Type of Precipitant on the Structure of Phase-inversion Polyamido-imide Membranes
Random Terpolymer Based on Simple Siloxane-functionalized Thiophene Unit Enabling High-performance Non-fullerene Organic Solar Cells
Circularly Polarized Luminescence Based on Helical Polymers: Structure-Property Relationships and Regulation Mechanisms
Related Author
Yang Yi
Shen-Bo Zhu
Ming-Hao Jin
Jia-Yin Lyu
Zhi-Bo Wang
Rui-Han Li
Xiao-Nan Xu
Xue-Chen Jiao
Related Institution
National Synchrotron Radiation Laboratory, University of Science and Technology of China
State Key Laboratory of Advanced Fiber Materials, College of Materials Science and Engineering, Donghua University
Shandong Runde Composite Materials Co., Ltd.
State Key Laboratory of Organic-Inorganic Composites & Beijing Key Laboratory of Advanced Functional Polymer Composites, Beijing University of Chemical Technology
Saint-Petersburg State Technological Institute (Technical University), Saint-Petersburg