Triphenylphosphine as Reducing Agent for Copper(II)-catalyzed AGET ATRP

Liang-jiu Bai; Wen-xiang Wang; Ming-hua Wang; Jin-ming Sun; Hou Chen

doi:10.1007/s10118-015-1676-1

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Triphenylphosphine as Reducing Agent for Copper(II)-catalyzed AGET ATRP

PAPER | Updated：2021-06-21

- Triphenylphosphine as Reducing Agent for Copper(II)-catalyzed AGET ATRP
- Chinese Journal of Polymer Science Vol. 33, Issue 9, Pages: 1260-1270(2015)
- Affiliations：
  
  School of Chemistry and Materials Science, Ludong University, Yantai 264025, China
- Author bio：
  
  **Liang-jiu Bai (柏良久), E-mail: bailiangjiu@163.com
  Hou Chen (陈厚), E-mail: lduchenhou@126.com
- Funds：
- DOI：10.1007/s10118-015-1676-1
  CLC：
- Received：27 January 2015，
  
  Revised：2015-03-24，
  
  Accepted：25 March 2015，
  
  Published：2015-09
- Accepted：
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Liang-jiu Bai, Wen-xiang Wang, Ming-hua Wang, et al. Triphenylphosphine as Reducing Agent for Copper(II)-catalyzed AGET ATRP[J]. Chinese Journal of Polymer Science, 2015, 33(9): 1260-1270.
DOI：

Liang-jiu Bai, Wen-xiang Wang, Ming-hua Wang, et al. Triphenylphosphine as Reducing Agent for Copper(II)-catalyzed AGET ATRP[J]. Chinese Journal of Polymer Science, 2015, 33(9): 1260-1270. DOI： 10.1007/s10118-015-1676-1.

摘要

Abstract

Triphenylphosphine (TPP) was used as reducing agent to continuously generate the Cu(I) activator in copper(II)- catalyzed activators generated by electron transfer atom transfer radical polymerization (AGET ATRP). For example

the polymers prepared with a molar ratio of [MMA]

/[EBiB]

/[CuCl

]

/[PMDETA]

/[TPP]

= 500/1/0.1/0.5/0.5 had controlled molecular weights and low molecular weight distribution (

) values (~1.2). TPP as a commercial reducing agent provides a convenient copper-catalyzed AGET ATRP procedure for the preparation of well-defined polymers.

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