Polypeptide Brushes Grown <italic style="font-style: italic">via</italic> Surface-initiated Ring-opening Polymerization of <italic style="font-style: italic">α</italic>-Amino Acid N-Carboxyanhydrides

Yong Shen; Zhibo Li; Harm-Anton Klok

doi:10.1007/s10118-015-1654-7

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Polypeptide Brushes Grown via Surface-initiated Ring-opening Polymerization of α-Amino Acid N-Carboxyanhydrides

REVIEW | Updated：2021-06-21

- Polypeptide Brushes Grown via Surface-initiated Ring-opening Polymerization of α-Amino Acid N-Carboxyanhydrides
- Chinese Journal of Polymer Science Vol. 33, Issue 7, Pages: 931-946(2015)
- Affiliations：
  
  a.School of Polymer Science and Engineering, Qingdao University of Science and Technology, Qingdao 266042, China
  b.Laboratory of Polymer Physics and Chemistry, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
  c.École Polytechnique Fédérale de Lausanne (EPFL), Institut des Matériaux and Institut des Sciences et Ingénierie Chimiques, Laboratoire des Polymères, Bâtiment MXD, Station 12, CH-1015 Lausanne, Switzerland
- Author bio：
  
  **Zhibo Li (李志波), E-mail: zbli@qust.edu.cn
  Harm-Anton Klok, E-mail: harm-anton.klok@epfl.ch
- Funds：
- DOI：10.1007/s10118-015-1654-7
  CLC：
- Received：16 March 2015，
  
  Accepted：22 March 2015，
  
  Published：2015-07
- Accepted：
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Yong Shen, Zhibo Li, Harm-Anton Klok. Polypeptide Brushes Grown via Surface-initiated Ring-opening Polymerization of α-Amino Acid N-Carboxyanhydrides[J]. Chinese Journal of Polymer Science, 2015, 33(7): 931-946. DOI: 10.1007/s10118-015-1654-7.
DOI：

Yong Shen, Zhibo Li, Harm-Anton Klok. Polypeptide Brushes Grown via Surface-initiated Ring-opening Polymerization of α-Amino Acid N-Carboxyanhydrides[J]. Chinese Journal of Polymer Science, 2015, 33(7): 931-946. DOI: 10.1007/s10118-015-1654-7. DOI：

摘要

Abstract

Polypeptide brushes are attractive platforms to generate functional and responsive interfaces that are of potential interest due to their possible biodegradability

biocompatibility and tunable secondary structures. Surface-initiated ring-opening polymerization (SI-ROP) of

-amino acid

-carboxyanhydrides represents a powerful and versatile strategy to generate polypeptide brushes. This review is an attempt to capture the state-of-the-art in this field and highlights the latest developments in several selected areas. In addition to presenting an overview of the synthetic methods that have been used to generate polypeptide brushes

via

SI-ROP

this article will discuss the preparation of patterned polypeptide brushes

the conformational properties of surface-tethered polypeptides

ways to control chain orientation at surfaces as well as properties and applications of these thin polymer films.

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Polypeptide Brushes Grown via Surface-initiated Ring-opening Polymerization of α-Amino Acid N-Carboxyanhydrides

DOI：10.1007/s10118-015-1654-7

摘要

Abstract

关键词

Keywords

references