Toughening of Poly(propylene carbonate) by Carbon Dioxide Copolymer Poly(urethane-amine) <italic style="font-style: italic">via</italic> Hydrogen Bonding Interaction

Lin Gu; Qing-yun Wu; Hai-bin Yu

doi:10.1007/s10118-015-1633-z

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Toughening of Poly(propylene carbonate) by Carbon Dioxide Copolymer Poly(urethane-amine) via Hydrogen Bonding Interaction

PAPER | Updated：2021-06-21

- Toughening of Poly(propylene carbonate) by Carbon Dioxide Copolymer Poly(urethane-amine) via Hydrogen Bonding Interaction
- Chinese Journal of Polymer Science Vol. 33, Issue 6, Pages: 838-849(2015)
- Affiliations：
  
  a.Key Laboratory of Marine New Materials and Application Technology, Zhejiang Key Laboratory of Marine Materials and Protective Technologies, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201, China
  b.Department of Polymer Science and Engineering, Faculty of Materials Science and Chemical Engineering, Ningbo University, Ningbo 315211, China
- Author bio：
  
  *Lin Gu (顾林), E-mail: gulin@nimte.ac.cn
  Hai-bin Yu (余海斌), E-mail: haibinyu@nimte.ac.cn
- Funds：
- DOI：10.1007/s10118-015-1633-z
  CLC：
- Received：28 September 2014，
  
  Revised：2014-10-11，
  
  Accepted：12 October 2014，
  
  Published：2015-06
- Accepted：
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Lin Gu, Qing-yun Wu, Hai-bin Yu. Toughening of Poly(propylene carbonate) by Carbon Dioxide Copolymer Poly(urethane-amine) via Hydrogen Bonding Interaction[J]. Chinese Journal of Polymer Science, 2015, 33(6): 838-849. DOI: 10.1007/s10118-015-1633-z.
DOI：

Lin Gu, Qing-yun Wu, Hai-bin Yu. Toughening of Poly(propylene carbonate) by Carbon Dioxide Copolymer Poly(urethane-amine) via Hydrogen Bonding Interaction[J]. Chinese Journal of Polymer Science, 2015, 33(6): 838-849. DOI: 10.1007/s10118-015-1633-z. DOI：

摘要

Abstract

A carbon dioxide copolymer poly(urethane-amine) (PUA) was blended with poly(propylene carbonate) (PPC) in order to improve the toughness and flexibility of PPC without sacrificing other mechanical properties. Compared with pure PPC

the PPC/PUA blend with 5 wt% PUA loading showed a 400% increase in elongation at break

whilst the corresponding yielding strength remained as high as 33.5 MPa and Young’s modulus showed slightly decrease. The intermolecular hydrogen bonding interaction in PPC/PUA blends was comfirmed by FTIR

2D IR and XPS spectra analysis

and finely dispersed particulate structure of PUA in PPC was observed in the SEM images

which provided good evidence for the toughening mechanism of PPC.

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Toughening of Poly(propylene carbonate) by Carbon Dioxide Copolymer Poly(urethane-amine) via Hydrogen Bonding Interaction

DOI：10.1007/s10118-015-1633-z

摘要

Abstract

关键词

Keywords

references