The Crystallization Behavior of Biodegradable Poly(butylene succinate) in the Presence of Organically Modified Clay with a Wide Range of Loadings

Jing-bin Chen; Jia-zhuang Xu; Huan Xu; Zhong-ming Li; Gan-ji Zhong; Jun Lei

doi:10.1007/s10118-015-1608-0

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The Crystallization Behavior of Biodegradable Poly(butylene succinate) in the Presence of Organically Modified Clay with a Wide Range of Loadings

PAPER | Updated：2021-06-21

- The Crystallization Behavior of Biodegradable Poly(butylene succinate) in the Presence of Organically Modified Clay with a Wide Range of Loadings
- Chinese Journal of Polymer Science Vol. 33, Issue 4, Pages: 576-586(2015)
- Affiliations：
  
  College of Polymer Science and Engineering and State Key Laboratory of Polymer Materials Engineering, Sichuan University, Chengdu 610065, China
- Author bio：
  
  **Gan-ji Zhong (钟淦基), E-mail: ganji.zhong@scu.edu.cn
  Jun Lei (雷军), E-mail: leijun@scu.edu.cn
- Funds：
- DOI：10.1007/s10118-015-1608-0
  CLC：
- Received：23 July 2014，
  
  Revised：2014-08-28，
  
  Accepted：13 September 2014，
  
  Published：2015-04
- Accepted：
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Jing-bin Chen, Jia-zhuang Xu, Huan Xu, et al. The Crystallization Behavior of Biodegradable Poly(butylene succinate) in the Presence of Organically Modified Clay with a Wide Range of Loadings[J]. Chinese Journal of Polymer Science, 2015, 33(4): 576-586.
DOI：

Jing-bin Chen, Jia-zhuang Xu, Huan Xu, et al. The Crystallization Behavior of Biodegradable Poly(butylene succinate) in the Presence of Organically Modified Clay with a Wide Range of Loadings[J]. Chinese Journal of Polymer Science, 2015, 33(4): 576-586. DOI： 10.1007/s10118-015-1608-0.

摘要

Abstract

The crystallization behavior of poly(butylene succinate) (PBS) nanocomposites with a wide range of contents of clays was revealed. It was of interest to find that the crystallization rate of PBS was accelerated obviously at relatively low contents of clays; while a retarded crystallization kinetics and a decreased crystallinity of PBS were found in the nanocomposites with higher clay contents. Two interplaying effects existed in the nanocomposites

i.e.

a suppression effect of clays on nucleation and a templating effect of clays on crystal growth

were clarified to contribute to this intriguing crystallization behavior.

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