Synthesis and Characterization of Heterocyclic Functionalized Polymers by Click Reaction: Preparation of Magnetic Nanocomposites and Studies on Their Thermal, Mechanical, Photophysical and Metal Ions Removal Properties

Mousa Ghaemy; Sahar Shabzendedar; Mehdi Taghavi

doi:10.1007/s10118-015-1583-5

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Synthesis and Characterization of Heterocyclic Functionalized Polymers by Click Reaction: Preparation of Magnetic Nanocomposites and Studies on Their Thermal, Mechanical, Photophysical and Metal Ions Removal Properties

PAPER | Updated：2022-01-17

- Synthesis and Characterization of Heterocyclic Functionalized Polymers by Click Reaction: Preparation of Magnetic Nanocomposites and Studies on Their Thermal, Mechanical, Photophysical and Metal Ions Removal Properties
- Chinese Journal of Polymer Science Vol. 33, Issue 2, Pages: 301-317(2015)
- Affiliations：
  
  Polymer Chemistry Research Laboratory, Department of Chemistry, University of Mazandaran, Babolsar, 47416-95447, I.R. Iran
- Author bio：
  
  *Mousa Ghaemy, E-mail: ghaemy@umz.ac.ir
- Funds：
- DOI：10.1007/s10118-015-1583-5
  CLC：
- Received：23 April 2014，
  
  Revised：2014-06-18，
  
  Accepted：02 July 2014，
  
  Published：2015-02
- Accepted：
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Mousa Ghaemy, Sahar Shabzendedar, Mehdi Taghavi. Synthesis and Characterization of Heterocyclic Functionalized Polymers by Click Reaction: Preparation of Magnetic Nanocomposites and Studies on Their Thermal, Mechanical, Photophysical and Metal Ions Removal Properties[J]. Chinese Journal of Polymer Science, 2015, 33(2): 301-317.
DOI：

Mousa Ghaemy, Sahar Shabzendedar, Mehdi Taghavi. Synthesis and Characterization of Heterocyclic Functionalized Polymers by Click Reaction: Preparation of Magnetic Nanocomposites and Studies on Their Thermal, Mechanical, Photophysical and Metal Ions Removal Properties[J]. Chinese Journal of Polymer Science, 2015, 33(2): 301-317. DOI： 10.1007/s10118-015-1583-5.

摘要

Abstract

This work reports synthesis and characterization of heterocyclic functionalized polymers

poly(triazole-ether-imidazole) s (PTAEI)

from a dialkyne-terminated compound

3-(4

5-bis(4-(propargyloxy)phenyl)-1H-imidazol-2-yl)-9-ethyl-9H-carbazole

by using click reaction. PTAEIs were characterized and their properties such as solubility

thermal

mechanical

photophysical and metal ions adsorption were investigated. These polymers had weight average molar masses (

) in the range of 19100-26700 g/mol

exhibited excellent solubility in polar aprotic solvents and formed low-colored flexible thin films by solution casting method. They exhibited good thermal stability with glass transition temperatures (

) between 160 °C and 211 °C and 10% weight loss temperatures (T10%) in the range of 308-426 °C. Nanocomposites of PTAEIs with epoxide-terminated Fe

showed that strong interfacial interaction between inorganic particles and the polymer matrix contributed to the enhanced thermal and mechanical properties. The photoluminescence intensity of the PTAEIs increased and the spectra red shifted with increasing Fe

content. The PTAEIs and nanocomposites were tested for their extraction capability of metal ions from aqueous solutions either individually or in the mixture.

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