Synthesis and MALDI-TOF Characterization of <italic style="font-style: italic">β</italic>-CD Core ATRP Initiators and RAFT Chain Transfers with Different Degrees of Substitution

Yan Xin; Hong Wang; Bo-wen Liu; Jin-ying Yuan

doi:10.1007/s10118-015-1572-8

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Synthesis and MALDI-TOF Characterization of β-CD Core ATRP Initiators and RAFT Chain Transfers with Different Degrees of Substitution

PAPER | Updated：2021-06-21

- Synthesis and MALDI-TOF Characterization of β-CD Core ATRP Initiators and RAFT Chain Transfers with Different Degrees of Substitution
- Chinese Journal of Polymer Science Vol. 33, Issue 1, Pages: 36-48(2015)
- Affiliations：
  
  Key Lab of Organic Optoelectronics and Molecular Engineering of Ministry of Education, Department of Chemistry, Tsinghua University, Beijing 100084, China
- Author bio：
  
  **Jin-ying Yuan (袁金颖), E-mail: yuanjy@mail.tsinghua.edu.cn
- Funds：
- DOI：10.1007/s10118-015-1572-8
  CLC：
- Received：17 March 2014，
  
  Revised：2014-04-20，
  
  Accepted：04 May 2014，
  
  Published：2015-01
- Accepted：
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Yan Xin, Hong Wang, Bo-wen Liu, et al. Synthesis and MALDI-TOF Characterization of β-CD Core ATRP Initiators and RAFT Chain Transfers with Different Degrees of Substitution[J]. Chinese Journal of Polymer Science, 2015, 33(1): 36-48. DOI: 10.1007/s10118-015-1572-8.
DOI：

Yan Xin, Hong Wang, Bo-wen Liu, et al. Synthesis and MALDI-TOF Characterization of β-CD Core ATRP Initiators and RAFT Chain Transfers with Different Degrees of Substitution[J]. Chinese Journal of Polymer Science, 2015, 33(1): 36-48. DOI: 10.1007/s10118-015-1572-8. DOI：

摘要

Abstract

In this paper

three different kinds of

-CD derivatives were synthesized as atom transfer radical polymerization (ATRP) initiator or reversible addition-fragmentation chain transfer polymerization (RAFT) chain transfers. The degree of substitution for each derivative was carefully characterized through

H-NMR

C-NMR spectroscopy and matrix-assisted laser desorption/ionization time of flight mass spectrometry (MALDI-TOF-MS). The factors influencing the degree of substitution were discussed. Moreover

the comparison between ATRP and RAFT was shown in the polymerization of

-isopropyl acrylamide (NIPAM).

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Synthesis and MALDI-TOF Characterization of β-CD Core ATRP Initiators and RAFT Chain Transfers with Different Degrees of Substitution

DOI：10.1007/s10118-015-1572-8

摘要

Abstract

关键词

Keywords

references