Morphological Studies on Sn-O Coordination Driving Self-assembly of Well-defined Organotin-containing Block Copolymers

Jian Jiang; Wei Yan; Ling-yan Liu; Wei-xing Chang; Jing Li

doi:10.1007/s10118-014-1546-2

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Morphological Studies on Sn-O Coordination Driving Self-assembly of Well-defined Organotin-containing Block Copolymers

Updated：2021-06-21

- Morphological Studies on Sn-O Coordination Driving Self-assembly of Well-defined Organotin-containing Block Copolymers
- Chinese Journal of Polymer Science Vol. 32, Issue 12, Pages: 1655-1665(2014)
- Affiliations：
  
  The State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Collaborative Innovation Center of Chemical Science and Engineering, Tianjin 300071, China
- Author bio：
  
  **Ling-yan Liu (柳凌艳), E-mail: liulingyan@nankai.edu.cn
  Jing Li (李靖), E-mail: lijing@nankai.edu.cn
- Funds：
- DOI：10.1007/s10118-014-1546-2
  CLC：
- Received：24 March 2014，
  
  Revised：2014-04-29，
  
  Accepted：13 May 2014，
  
  Published：2014-12
- Accepted：
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Jian Jiang, Wei Yan, Ling-yan Liu, et al. Morphological Studies on Sn-O Coordination Driving Self-assembly of Well-defined Organotin-containing Block Copolymers[J]. Chinese Journal of Polymer Science, 2014, 32(12): 1655-1665.
DOI：

Jian Jiang, Wei Yan, Ling-yan Liu, et al. Morphological Studies on Sn-O Coordination Driving Self-assembly of Well-defined Organotin-containing Block Copolymers[J]. Chinese Journal of Polymer Science, 2014, 32(12): 1655-1665. DOI： 10.1007/s10118-014-1546-2.

摘要

Abstract

A tin-oxygen coordination driving self-assembly was developed in the block copolymers containing organotin

which were prepared by the radical addition-fraction transfer (RAFT) method and characterized by the gel-permeation chromatography (GPC) and

H-NMR. And the self-assemblies of these block copolymers with various chain length ratios in the different concentrations in CHCl3 were stable according to the results of DLS and TEM. Additionally

it was also given an insight investigation on the regulation of self-assembly of the block copolymers by adding dibutyltin dichloride and a possible mechanism was proposed.

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