Photo-induced Living Cationic Copolymerization of Isobutyl Vinyl Ether and Vinyl Ether with Carbazolyl Groups

Ming Li; Li-fen Zhang; Mei-xia Tao; Zhen-ping Cheng; Xiu-lin Zhu

doi:10.1007/s10118-014-1540-8

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Photo-induced Living Cationic Copolymerization of Isobutyl Vinyl Ether and Vinyl Ether with Carbazolyl Groups

Updated：2021-06-21

- Photo-induced Living Cationic Copolymerization of Isobutyl Vinyl Ether and Vinyl Ether with Carbazolyl Groups
- Chinese Journal of Polymer Science Vol. 32, Issue 11, Pages: 1564-1574(2014)
- Affiliations：
  
  Suzhou Key Laboratory of Macromolecular Design and Precision Synthesis, Jiangsu Key Laboratory of Advanced Functional Polymer Design and Application, Department of Polymer Science and Engineering, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, China
- Author bio：
  
  **Li-fen Zhang (张丽芬), E-mail: zhanglifen@suda.edu.cn
  Zhen-ping Cheng (程振平), E-mail: chengzhenping@suda.edu.cn
- Funds：
- DOI：10.1007/s10118-014-1540-8
  CLC：
- Received：27 January 2014，
  
  Revised：2014-03-08，
  
  Accepted：25 March 2014，
  
  Published：2014-11
- Accepted：
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Ming Li, Li-fen Zhang, Mei-xia Tao, et al. Photo-induced Living Cationic Copolymerization of Isobutyl Vinyl Ether and Vinyl Ether with Carbazolyl Groups[J]. Chinese Journal of Polymer Science, 2014, 32(11): 1564-1574.
DOI：

Ming Li, Li-fen Zhang, Mei-xia Tao, et al. Photo-induced Living Cationic Copolymerization of Isobutyl Vinyl Ether and Vinyl Ether with Carbazolyl Groups[J]. Chinese Journal of Polymer Science, 2014, 32(11): 1564-1574. DOI： 10.1007/s10118-014-1540-8.

摘要

Abstract

In this work

a fluorescent monomer 2-(9-carbazolyl) ethyl vinyl ether (CEVE) was synthesized in our lab

and its photo-induced living cationic copolymerization behavior with isobutyl vinyl ether (IBVE) was investigated in detail using diphenyliodonium chloride (DPICl)/2

2-dimethoxy-2-phenylacetophenone (DMPA) and zinc bromide (ZnBr

) initiating system in dichloromethane solution at 5 ℃

−5 ℃

and −15 ℃

respectively. The living nature of this copolymerization system was confirmed by adding fresh comonomer method after the copolymerization almost finished. In addition

the obtained fluorescent copolymer poly(IBVE-

-CEVE) has a low glass transition temperature (

)

below −10 ℃.

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