Organosoluble Aliphatic-Aromatic Poly(ether-amide)s Based on Pyridine Moiety in the Main Chain: Synthesis, Characterization and Thermal Studies

Mohsen Hajibeygi; Meisam Shabanian

doi:10.1007/s10118-014-1449-2

Your Location：

Home >

Browse articles >

Organosoluble Aliphatic-Aromatic Poly(ether-amide)s Based on Pyridine Moiety in the Main Chain: Synthesis, Characterization and Thermal Studies

Updated：2021-06-21

- Organosoluble Aliphatic-Aromatic Poly(ether-amide)s Based on Pyridine Moiety in the Main Chain: Synthesis, Characterization and Thermal Studies
- Chinese Journal of Polymer Science Vol. 32, Issue 6, Pages: 758-767(2014)
- Affiliations：
  
  a.Young Researchers Club, Varamin Pishva Branch, Islamic Azad University, Varamin, Iran
  b.Department of Chemistry, Farahan Branch, Islamic azad University, Farahan, Iran
- Author bio：
  
  *Mohsen Hajibeygi, E-mail: mhajibeygi@iauvaramin.ac.ir or mhajibeygi@gmail.com
- Funds：
- DOI：10.1007/s10118-014-1449-2
  CLC：
- Received：09 September 2013，
  
  Revised：2013-12-20，
  
  Accepted：31 December 2013，
  
  Published：2014-06
- Accepted：
Scan QR Code
Mohsen Hajibeygi, Meisam Shabanian. Organosoluble Aliphatic-Aromatic Poly(ether-amide)s Based on Pyridine Moiety in the Main Chain: Synthesis, Characterization and Thermal Studies[J]. Chinese Journal of Polymer Science, 2014, 32(6): 758-767.
DOI：

Mohsen Hajibeygi, Meisam Shabanian. Organosoluble Aliphatic-Aromatic Poly(ether-amide)s Based on Pyridine Moiety in the Main Chain: Synthesis, Characterization and Thermal Studies[J]. Chinese Journal of Polymer Science, 2014, 32(6): 758-767. DOI： 10.1007/s10118-014-1449-2.

摘要

Abstract

A series organosoluble and heterocyclic poly(ether-amide)s (PEA)s were synthesized from a new diamine containing pyridine moiety and four aliphatic-aromatic dicarboxylic acids by direct polycondensation reactions. Dicarboxilic acids

4a−4d

containing ether groups were synthesized in two steps reactions. At first

dialdehydes

3a−3d

were synthesized from four dibromo alkanes

1a−1d

and 4-hydroxybenzaldehyde

then dicarboxilic acids

4a−4d

were synthesized from dialdehydes

3a−3d

and malonic acid in a solvent free reaction. On the other hand

the new diamine

containing pyridine ring was synthesized in two step reactions. The structures of synthesized monomers and polymers were provn by FTIR

NMR spectroscopy and elemental analysis. Also all of the above polymers were fully characterized by inherent viscosity

solubility tests

gel permeation chromatography (GPC)

differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA). The resulted PEAs have shown good inherent viscosities

solubility and thermal properties.

关键词

Keywords

references

Views

Downloads

CSCD

Alert me when the article has been cited

Submit

Tools

Publicity Resources

Cross-linked Polyamides Prepared through Direct Bulk Michael Addition and Polycondensation from 1,6-Hexanediamine and Methyl Acrylate

Preparation and Characterization of Flexible, Transparent and Thermally Stable Aromatic Co-polyamides

Synthesis and Characterization of S,N-Heteroacenes by Bischler-Napieralski Reaction

Synthesis of Poly(butylene terephthalate)-Poly(tetramethylene glycol) Copolymers Using Terephthalic Acid as Starting Material: A Comparation between Two Synthetic Strategies

Thermally Stable and Organo-soluble Polyamides Containing Triazine Rings and Ether Linkages in the Main Chain: Synthesis and Characterization

Related Author

Jin-Nan Zhao

Jing-Bo Zhao

Zhi-Yuan Zhang

Jun-Ying Zhang

Sheng-Qing Yang

José Antonio Tec-Sánchez

Andrés Iván Oliva Arias

Manuel Aguilar-Vega

Related Institution

Key Laboratory of Carbon Fiber and Functional Polymers (Beijing University of Chemical Technology), Ministry of Education; College of Materials Science and Engineering, Beijing University of Chemical Technology

Unidad de Materiales, Centro de Investigación Científica de Yucatán A. C., Calle 43 No.130 x 32 y 34, Col. Chuburná de Hidalgo, C.P. 97205, Mérida, Yucatán, México

Centro de Investigación y de Estudios Avanzados del IPN, Unidad Mérida, Departamento de Física Aplicada, Km. 6 Antigua Carretera a Progreso, AP 73-Cordemex, Mérida Yucatán97310, México

School of Chemical and Environmental Engineering, Shanghai Institute of Technology

Tianjin Key Laboratory of Molecular Optoelectronic Science, Tianjin University

⁰