Synthesis and Optical Properties of Hyperbranched PAEKs Containing Porphyrin and Its Metal Derivatives

Xu Jiang; Yin-long Du; Chuan Liu; Peng-fei Huo; Zhi Geng; Shu-ling Zhang; Gui-bin Wang

doi:10.1007/s10118-014-1375-3

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Synthesis and Optical Properties of Hyperbranched PAEKs Containing Porphyrin and Its Metal Derivatives

Updated：2021-06-21

- Synthesis and Optical Properties of Hyperbranched PAEKs Containing Porphyrin and Its Metal Derivatives
- Chinese Journal of Polymer Science Vol. 32, Issue 1, Pages: 73-83(2014)
- Affiliations：
  
  College of Chemistry, Engineering Research Center of High Performance Plastics, Ministry of Education, Jilin University, Changchun 130012, China
- Author bio：
  
  **Gui-bin Wang (王贵宾), E-mail: wgb@jlu.edu.cn
- Funds：
- DOI：10.1007/s10118-014-1375-3
  CLC：
- Received：18 February 2013，
  
  Revised：2013-04-26，
  
  Accepted：06 May 2013，
  
  Published：2014-01
- Accepted：
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Xu Jiang, Yin-long Du, Chuan Liu, et al. Synthesis and Optical Properties of Hyperbranched PAEKs Containing Porphyrin and Its Metal Derivatives[J]. Chinese Journal of Polymer Science, 2014, 32(1): 73-83.
DOI：

Xu Jiang, Yin-long Du, Chuan Liu, et al. Synthesis and Optical Properties of Hyperbranched PAEKs Containing Porphyrin and Its Metal Derivatives[J]. Chinese Journal of Polymer Science, 2014, 32(1): 73-83. DOI： 10.1007/s10118-014-1375-3.

摘要

Abstract

Novel functional hyperbranched poly(aryl ether ketone)s (HPAEKs) bonded with nonlinear optical chromophores (meso-tetrakis(4-hydroxyphenyl) porphyrin

THPP and its metal derivatives) were synthesized and characterized by

H-NMR and UV-Vis absorption spectra. The incorporation of chromophores into HPAEKs endowed HPAEKs novel NLO and OL properties. Indeed

dendritic architecture allowed for maximum dispersion of the chromophores

avoided aggregation

more optical limiting property was obtained. Simultaneously

they retained the excellent properties of the materials

particularly in thermal stability. Their optical properties were evaluated by nonlinear optical analyses and optical limiting. The results showed that these polymers possessed good optical limiting (OL) property and large nonlinear optical (NLO) susceptibilities (

. 10

−12

esu). All polymers containing chromophores presented excellent thermal stability (

524.17 ℃).

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