SYNTHESIS OF EXFOLIATED ISOTACTIC POLYPROPYLENE/FUNCTIONAL ALKYL-TRIPHENYLPHOSPHONIUM-MODIFIED CLAY NANOCOMPOSITES BY <italic style="font-style: italic">IN SITU</italic> POLYMERIZATION

Kai Du; Ai-hua He; Fu-yong Bi; Charles C. Han

doi:10.1007/s10118-013-1351-3

Your Location：

Home >

Browse articles >

SYNTHESIS OF EXFOLIATED ISOTACTIC POLYPROPYLENE/FUNCTIONAL ALKYL-TRIPHENYLPHOSPHONIUM-MODIFIED CLAY NANOCOMPOSITES BY IN SITU POLYMERIZATION

PAPER | Updated：2023-01-03

- SYNTHESIS OF EXFOLIATED ISOTACTIC POLYPROPYLENE/FUNCTIONAL ALKYL-TRIPHENYLPHOSPHONIUM-MODIFIED CLAY NANOCOMPOSITES BY IN SITU POLYMERIZATION
- Chinese Journal of Polymer Science Vol. 31, Issue 11, Pages: 1501-1508(2013)
- Affiliations：
  
  a.Fine Chemicals Department, Beijing Research Institute of Chemical Industry, SINOPEC, Beijing 100013, China
  b.Key Laboratory of Rubber-Plastics, Ministry of Education/Shandong Provincial Key Laboratory of Rubber-Plastics, School of Polymer Science and Engineering, Qingdao University of Science and Technology, Qingdao 266042, China
  c.State Key Laboratory of Polymer Physics and Chemistry, Joint Laboratory of Polymer Science and Materials, Beijing National Laboratory for Molecular Science, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
- Author bio：
  
  **Ai-hua He (贺爱华), E-mail: ahhe@qust.edu.cn
- Funds：
- DOI：10.1007/s10118-013-1351-3
  CLC：
- Received：20 November 2012，
  
  Revised：2013-01-06，
  
  Accepted：14 January 2013，
  
  Published：2013-11
- Accepted：
Scan QR Code
Kai Du, Ai-hua He, Fu-yong Bi, et al. SYNTHESIS OF EXFOLIATED ISOTACTIC POLYPROPYLENE/FUNCTIONAL ALKYL-TRIPHENYLPHOSPHONIUM-MODIFIED CLAY NANOCOMPOSITES BY IN SITU POLYMERIZATION[J]. Chinese Journal of Polymer Science, 2013, 31(11): 1501-1508. DOI: 10.1007/s10118-013-1351-3.
DOI：

Kai Du, Ai-hua He, Fu-yong Bi, et al. SYNTHESIS OF EXFOLIATED ISOTACTIC POLYPROPYLENE/FUNCTIONAL ALKYL-TRIPHENYLPHOSPHONIUM-MODIFIED CLAY NANOCOMPOSITES BY IN SITU POLYMERIZATION[J]. Chinese Journal of Polymer Science, 2013, 31(11): 1501-1508. DOI: 10.1007/s10118-013-1351-3. DOI：

摘要

Abstract

Diphenyl (4-hydroxyphenyl) hexadecyl phosphonium bromide (POH) -modified montmorillonite (POHMMT) was used to prepare a novel TiCl

/MgCl

/POHMMT compound catalyst and exfoliated

PP/POHMMT nanocomposites were prepared by the

in situ

intercalative polymerization of propylene with the TiCl

/MgCl

/POHMMT compound catalyst. The POH surfactants don’t change the catalytic characteristic of the Z-N catalyst and the obtained PP presents high isotacticity

normal molecular weight and molecular weight distribution. The WAXD

SAXS and TEM results demonstrate the highly exfoliated

PP/POHMMT nanocomposites were produced by the

in situ

polymerization with this novel catalyst

while the intercalated

PP/ Na

MMT nanocomposites were produced with the TiCl

/MgCl

/Na

MMT compound catalyst. Through this approach

in situ

propylene polymerization can actually take place between the silicate layers and lead not only to PP with high isotacticity and molecular weight

but also to highly exfoliated PP nanocomposites.

关键词

Keywords

references

Views

120

Downloads

CSCD

Alert me when the article has been cited

Submit

Tools

Publicity Resources

Poly(vinyl alcohol)/GO-MMT Nanocomposites: Preparation, Structure and Properties

Effect of Nanoclay on the Phase Separation Behavior of Poly(methyl methacrylate)/Poly(vinyl acetate) Binary Polymer Blends

Studies on Crystal Transition of Polyamide 11 Nanocomposites by Variable-temperature X-Ray Diffraction

INFLUENCE OF CLAY ON THE MORPHOLOGY AND PHASE SEPARATION BEHAVIOR OF POLY(METHYL METHACRYLATE)/POLY(STYRENE-co-ACRYLONITRILE) BLENDS

TOUGHENING OF ETHYLENE-PROPYLENE RANDOM COPOLYMER/CLAY NANOCOMPOSITES: COMPARISON OF DIFFERENT COMPATIBILIZERS

Related Author

Muhammad Raheel

Kun Yao

Jiang Gong

Xue-cheng Chen

Dong-tao Liu

Yi-chao Lin

Dong-mei Cui

Muhammad Siddiq

Related Institution

Department of Chemistry, Quaid-i-Azam University

State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences

Key Laboratory of Macromolecule Synthesis and Functionalization, Ministry of Education, Department of Polymer Science and Engineering, Zhejiang University

Institute of Materials Research and Engineering, A*STAR (Agency for Science, Technology and Research), 3 Research Link

State Key Laboratory of Molecular Engineering of Polymers, Department of Macromolecular Science, Fudan University

⁰

SYNTHESIS OF EXFOLIATED ISOTACTIC POLYPROPYLENE/FUNCTIONAL ALKYL-TRIPHENYLPHOSPHONIUM-MODIFIED CLAY NANOCOMPOSITES BY IN SITU POLYMERIZATION

DOI：10.1007/s10118-013-1351-3

摘要

Abstract

关键词

Keywords

references