Yan-ping Hao, Huan-huan Ge, Li-jing Han, et al. THERMAL AND MECHANICAL PROPERTIES OF POLYLACTIDE TOUGHENED WITH A BUTYL ACRYLATE-ETHYL ACRYLATE-GLYCIDYL METHACRYLATE COPOLYMER[J]. Chinese Journal of Polymer Science, 2013, 31(11): 1519-1527.
DOI:
Yan-ping Hao, Huan-huan Ge, Li-jing Han, et al. THERMAL AND MECHANICAL PROPERTIES OF POLYLACTIDE TOUGHENED WITH A BUTYL ACRYLATE-ETHYL ACRYLATE-GLYCIDYL METHACRYLATE COPOLYMER[J]. Chinese Journal of Polymer Science, 2013, 31(11): 1519-1527.DOI: 10.1007/s10118-013-1350-4.
THERMAL AND MECHANICAL PROPERTIES OF POLYLACTIDE TOUGHENED WITH A BUTYL ACRYLATE-ETHYL ACRYLATE-GLYCIDYL METHACRYLATE COPOLYMER
a specific polylactide (PLA) 4032D was melt-mixed with a new toughener: butyl acrylate (BA)
ethyl acrylate (EA) and glycidyl methacrylate (GMA) copolymer (BA-EA-GMA). DMA tests showed that PLA/BA-EA-GMA blends were partially miscible. The degree of crystallinity of PLA increased while the cold crystallization temperature shifted to higher temperatures with increasing BA-EA-GMA content. The SEM micrographs showed that PLA/BA-EA-GMA blends had a good dispersion and this phenomenon was in good agreement with their higher impact strength. The result showed that the adding of BA-EA-GMA has enhanced the flexibility of PLA/BA-EA-GMA blends as compared with pure PLA. The impact strength was changed from 3.4 kJ/m2 for pure PLA to 29.6 kJ/m
2
for 80/20 PLA/BA-EA-GMA blend.
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