SECOND-ORDER NONLINEAR OPTICAL HYPERBRANCHED POLYMER CONTAINING ISOLATION CHROMOPHORE MOIETIES DERIVED FROM BOTH "H"-TYPE AND STAR-TYPE CHROMOPHORES

Wen-bo Wu; Ying-jie Fu; Can Wang; Zhen Xu; Cheng Ye; Jin-gui Qin; Zhen } Li

doi:10.1007/s10118-013-1343-3

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SECOND-ORDER NONLINEAR OPTICAL HYPERBRANCHED POLYMER CONTAINING ISOLATION CHROMOPHORE MOIETIES DERIVED FROM BOTH "H"-TYPE AND STAR-TYPE CHROMOPHORES

PAPER | Updated：2023-01-03

- SECOND-ORDER NONLINEAR OPTICAL HYPERBRANCHED POLYMER CONTAINING ISOLATION CHROMOPHORE MOIETIES DERIVED FROM BOTH "H"-TYPE AND STAR-TYPE CHROMOPHORES
- Chinese Journal of Polymer Science Vol. 31, Issue 10, Pages: 1415-1423(2013)
- Affiliations：
  
  a.Department of Chemistry, Hubei Key Lab on Organic and Polymeric Opto-Electronic Materials, Wuhan University, Wuhan 430072, China
  b.Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
- Author bio：
  
  **Zhen Li (李振), E-mail: lizhen@whu.edu.cn or lichemlab@163.com
- Funds：
- DOI：10.1007/s10118-013-1343-3
  CLC：
- Received：02 November 2012，
  
  Revised：2012-12-23，
  
  Accepted：04 January 2013，
  
  Published：2013-10
- Accepted：
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Wen-bo Wu, Ying-jie Fu, Can Wang, et al. SECOND-ORDER NONLINEAR OPTICAL HYPERBRANCHED POLYMER CONTAINING ISOLATION CHROMOPHORE MOIETIES DERIVED FROM BOTH "H"-TYPE AND STAR-TYPE CHROMOPHORES[J]. Chinese Journal of Polymer Science, 2013, 31(10): 1415-1423.
DOI：

Wen-bo Wu, Ying-jie Fu, Can Wang, et al. SECOND-ORDER NONLINEAR OPTICAL HYPERBRANCHED POLYMER CONTAINING ISOLATION CHROMOPHORE MOIETIES DERIVED FROM BOTH "H"-TYPE AND STAR-TYPE CHROMOPHORES[J]. Chinese Journal of Polymer Science, 2013, 31(10): 1415-1423. DOI： 10.1007/s10118-013-1343-3.

摘要

Abstract

An NLO hyperbranched polymer (HP1) derived from both "H"-type and star-type chromophores was synthesized successfully for the first time with high yield via one-pot "A

+ B

" Suzuki polymerization reaction. Isolation chromophore was also introduced to further improve its performance. Although under the test conditions

the films of HP1 could not be poled completely

it still demonstrated satisfactory macroscopic NLO effect with the second harmonic generation (SHG) coefficient

value of 36 pm/V.

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