SIMULATION STUDY OF CO-ASSEMBLY OF ABC TRIBLOCK COPOLYMER/NANOPARTICLE INTO MULTICOMPARTMENT HYBRIDS IN SELECTIVE SOLVENT

Jie Cui; Wei Li; Wei Jiang

doi:10.1007/s10118-013-1323-7

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SIMULATION STUDY OF CO-ASSEMBLY OF ABC TRIBLOCK COPOLYMER/NANOPARTICLE INTO MULTICOMPARTMENT HYBRIDS IN SELECTIVE SOLVENT

Special Issue: In Memory of Prof. Bingzheng Jiang | Updated：2023-01-03

- SIMULATION STUDY OF CO-ASSEMBLY OF ABC TRIBLOCK COPOLYMER/NANOPARTICLE INTO MULTICOMPARTMENT HYBRIDS IN SELECTIVE SOLVENT
- Chinese Journal of Polymer Science Vol. 31, Issue 9, Pages: 1225-1232(2013)
- Affiliations：
  
  State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, ChineseAcademy of Sciences, Changchun 130022, China
- Author bio：
  
  **Wei Jiang (姜伟), E-mail: wjiang@ciac.jl.cn
- Funds：
- DOI：10.1007/s10118-013-1323-7
  CLC：
- Received：21 March 2013，
  
  Revised：2013-05-17，
  
  Accepted：09 June 2013，
  
  Published：2013-09
- Accepted：
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Jie Cui, Wei Li, Wei Jiang. SIMULATION STUDY OF CO-ASSEMBLY OF ABC TRIBLOCK COPOLYMER/NANOPARTICLE INTO MULTICOMPARTMENT HYBRIDS IN SELECTIVE SOLVENT[J]. Chinese Journal of Polymer Science, 2013, 31(9): 1225-1232.
DOI：

Jie Cui, Wei Li, Wei Jiang. SIMULATION STUDY OF CO-ASSEMBLY OF ABC TRIBLOCK COPOLYMER/NANOPARTICLE INTO MULTICOMPARTMENT HYBRIDS IN SELECTIVE SOLVENT[J]. Chinese Journal of Polymer Science, 2013, 31(9): 1225-1232. DOI： 10.1007/s10118-013-1323-7.

摘要

Abstract

Co-assembly of ABC linear triblock copolymer/nanoparticle into bump-surface multicompartment hybrids in selective solvent was studied through self-consistent field theory (SCFT) simulation. Results from three-dimensional SCFT simulation showed that the hybrid morphology depended on the length and number of grafted chains

whereas the number and shape of bumps relied on nanoparticle size. Moreover

the simulation results showed that the length and number of grafted chains had equivalent effect on hybrid morphology. Calculated results indicated that entropy was a more important factor than enthalpy in the co-assembly.

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