SELF-ASSEMBLY OF LINEAR ROD-COIL MULTIBLOCK COPOLYMERS

Ying-dong Xia; Ji-zhong Chen; Tong-fei Shi; Li-jia An

doi:10.1007/s10118-013-1322-8

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SELF-ASSEMBLY OF LINEAR ROD-COIL MULTIBLOCK COPOLYMERS

Special Issue: In Memory of Prof. Bingzheng Jiang | Updated：2023-01-03

- SELF-ASSEMBLY OF LINEAR ROD-COIL MULTIBLOCK COPOLYMERS
- Chinese Journal of Polymer Science Vol. 31, Issue 9, Pages: 1242-1249(2013)
- Affiliations：
  
  State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
- Author bio：
  
  **Ji-zhong Chen (陈继忠), E-mail: jzchen@ciac.jl.cn
- Funds：
- DOI：10.1007/s10118-013-1322-8
  CLC：
- Received：21 March 2013，
  
  Revised：2013-05-24，
  
  Accepted：28 May 2013，
  
  Published：2013-09
- Accepted：
Scan QR Code
Ying-dong Xia, Ji-zhong Chen, Tong-fei Shi, et al. SELF-ASSEMBLY OF LINEAR ROD-COIL MULTIBLOCK COPOLYMERS[J]. Chinese Journal of Polymer Science, 2013, 31(9): 1242-1249.
DOI：

Ying-dong Xia, Ji-zhong Chen, Tong-fei Shi, et al. SELF-ASSEMBLY OF LINEAR ROD-COIL MULTIBLOCK COPOLYMERS[J]. Chinese Journal of Polymer Science, 2013, 31(9): 1242-1249. DOI： 10.1007/s10118-013-1322-8.

摘要

Abstract

The self-assembly of the linear rod-coil multiblock copolymers is studied by applying self-consistent-field lattice techniques in a three-dimensional (3D) space. Compared to the copolymer with one rod

the copolymer with more rods (

rod

≥ 2) exhibits rich order-order phase transitions with increasing temperature

where the ordered morphology changes from strips to perforated lamellae and finally to lamellae. In addition

taking the copolymer with

rod

= 2 as a representative

we further study the effects of the volume fractions of the rods

the spacer coils and the end coils on the phase behaviors respectively

by which the detailed self-assembled mechanism of the linear rod-coil multiblock copolymers is revealed. Our results are expected to provide guidance for the design of the rod-coil materials.

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