İsmet Kaya, Murat Gül. SYNTHESIS, CHARACTERIZATION AND SOME PROPERTIES OF EPOXY RESINS CONTAINING AZOMETHINE BONDING[J]. Chinese Journal of Polymer Science, 2013, 31(8): 1087-1095.
DOI:
İsmet Kaya, Murat Gül. SYNTHESIS, CHARACTERIZATION AND SOME PROPERTIES OF EPOXY RESINS CONTAINING AZOMETHINE BONDING[J]. Chinese Journal of Polymer Science, 2013, 31(8): 1087-1095.DOI: 10.1007/s10118-013-1293-9.
SYNTHESIS, CHARACTERIZATION AND SOME PROPERTIES OF EPOXY RESINS CONTAINING AZOMETHINE BONDING
New epoxy resins were prepared from hydroxyl substituted Schiff base monomers in two steps. The first step is based on the synthesis of hydroxyl substituted Schiff base monomers via condensation reaction. The second step includes the reaction between Schiff base monomers with epichlorohydrine (EPC) to obtain epoxy resins. The structures of resulting compounds were confirmed by FTIR and
1
H-NMR. TG-DTA and DSC measurements were made for thermal characterizations of the compounds. Chemical resistances of the cured epoxy-amine systems in acidic
alkaline and organic solvents were determined for coating applications. HCl (aqueous solution
10%)
NaOH (aqueous solution
10%)
DMSO
DMF
N-methylpyrrolidone
ethanol
THF and acetone were used for corrosion tests. Chemical resistance data show that the synthesized resins have good chemical resistance against various acid
alkaline and common organic solvents.
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