SYNTHESIS, PROPERTIES AND ELECTROPOLYMERIZATION OF STARSHAPED OLIGOTHIOPHENES WITH HEXAKIS(FLUOREN-2-YL)BENZENE AS CORE

Yang Zou; Yuan Liu; Jin-gui Qin; Chu-luo Yang

doi:10.1007/s10118-013-1286-8

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SYNTHESIS, PROPERTIES AND ELECTROPOLYMERIZATION OF STARSHAPED OLIGOTHIOPHENES WITH HEXAKIS(FLUOREN-2-YL)BENZENE AS CORE

Special Issue: In Honor of the 80th Birthday of Professor Fosong Wang (Part II) | Updated：2023-01-03

- SYNTHESIS, PROPERTIES AND ELECTROPOLYMERIZATION OF STARSHAPED OLIGOTHIOPHENES WITH HEXAKIS(FLUOREN-2-YL)BENZENE AS CORE
- Chinese Journal of Polymer Science Vol. 31, Issue 6, Pages: 938-945(2013)
- Affiliations：
  
  Department of Chemistry, Hubei Key Lab on Organic and Polymeric Opto-Electronic Materials, Wuhan University, Wuhan 430072, China
- Author bio：
  
  **Chu-luo Yang (杨楚罗), E-mail: clyang@whu.edu.cn
- Funds：
- DOI：10.1007/s10118-013-1286-8
  CLC：
- Received：17 January 2013，
  
  Revised：2013-02-03，
  
  Accepted：05 February 2013，
  
  Published：2013-06
- Accepted：
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Yang Zou, Yuan Liu, Jin-gui Qin, et al. SYNTHESIS, PROPERTIES AND ELECTROPOLYMERIZATION OF STARSHAPED OLIGOTHIOPHENES WITH HEXAKIS(FLUOREN-2-YL)BENZENE AS CORE[J]. Chinese Journal of Polymer Science, 2013, 31(6): 938-945.
DOI：

Yang Zou, Yuan Liu, Jin-gui Qin, et al. SYNTHESIS, PROPERTIES AND ELECTROPOLYMERIZATION OF STARSHAPED OLIGOTHIOPHENES WITH HEXAKIS(FLUOREN-2-YL)BENZENE AS CORE[J]. Chinese Journal of Polymer Science, 2013, 31(6): 938-945. DOI： 10.1007/s10118-013-1286-8.

摘要

Abstract

Star-shaped oligothiophenes with hexakis(fluoren-2-yl)benzene (HFB) as cores were designed and synthesized. Grafting thiophene units to HFB results in a bond flattening of the core

and makes the molecules a flipping-twist shape. Their thermal

photophysical and electrochemical properties were studied. Highly cross-linked conjugated polymers can be produced by electropolymerization of T1−T3.

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