PRECISE SYNTHESIS OF OLEFIN BLOCK COPOLYMERS USING A SYNDIOSPECIFIC LIVING POLYMERIZATION SYSTEM

Zheng-guo Cai; Hai-hui Su; Takeshi Shiono

doi:10.1007/s10118-013-1250-7

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PRECISE SYNTHESIS OF OLEFIN BLOCK COPOLYMERS USING A SYNDIOSPECIFIC LIVING POLYMERIZATION SYSTEM

Special Issue: Coordination Polymerization of Olefins | Updated：2023-01-03

- PRECISE SYNTHESIS OF OLEFIN BLOCK COPOLYMERS USING A SYNDIOSPECIFIC LIVING POLYMERIZATION SYSTEM
- Chinese Journal of Polymer Science Vol. 31, Issue 4, Pages: 541-549(2013)
- Affiliations：
  
  State Key Lab for Modification of Chemical Fibers and Polymer Materials, College of Material Science and Engineering, Donghua University, Shanghai 201620, China
  Graduate School of Engineering, Hiroshima University, Higashi-Hiroshima 739-8527, Japan
- Author bio：
  
  *Zheng-guo Cai (蔡正国), E-mail: caizg@dhu.edu.cn
  Takeshi Shiono, E-mail: tshiono@hiroshima-u.ac.jp
- Funds：
- DOI：10.1007/s10118-013-1250-7
  CLC：
- Received：01 November 2012，
  
  Revised：2012-11-19，
  
  Accepted：28 November 2012，
  
  Published：2013-04
- Accepted：
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Zheng-guo Cai, Hai-hui Su, Takeshi Shiono. PRECISE SYNTHESIS OF OLEFIN BLOCK COPOLYMERS USING A SYNDIOSPECIFIC LIVING POLYMERIZATION SYSTEM[J]. Chinese Journal of Polymer Science, 2013, 31(4): 541-549.
DOI：

Zheng-guo Cai, Hai-hui Su, Takeshi Shiono. PRECISE SYNTHESIS OF OLEFIN BLOCK COPOLYMERS USING A SYNDIOSPECIFIC LIVING POLYMERIZATION SYSTEM[J]. Chinese Journal of Polymer Science, 2013, 31(4): 541-549. DOI： 10.1007/s10118-013-1250-7.

摘要

Abstract

This feature article summarizes the synthesis of novel olefin block copolymers using fast syndiospecific living homo- and copolymerization of propylene

higher 1-alkene

and norbornene with

ansa

-fluorenylamidodimethyltitaniumbased catalyst according to the authors' recent results. The catalytic synthesis of monodisperse polyolefin and olefin block copolymer was also described using this living system.

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