PREPARATION, CHARACTERIZATION AND ADHESIVE PROPERTIES OF DI-AND TRI-HYDROXY BENZOYL CHITOSAN NANOPARTICLES

Mohamad Taghi Taghizadeh; Ali Bahadori

doi:10.1007/s10118-013-1247-2

Your Location：

Home >

Browse articles >

PREPARATION, CHARACTERIZATION AND ADHESIVE PROPERTIES OF DI-AND TRI-HYDROXY BENZOYL CHITOSAN NANOPARTICLES

PAPER | Updated：2023-01-03

- PREPARATION, CHARACTERIZATION AND ADHESIVE PROPERTIES OF DI-AND TRI-HYDROXY BENZOYL CHITOSAN NANOPARTICLES
- Chinese Journal of Polymer Science Vol. 31, Issue 4, Pages: 649-659(2013)
- Affiliations：
  
  Department of Physical Chemistry, Faculty of Chemistry, University of Tabriz, Tabriz, Iran
- Author bio：
  
  *Mohamad Taghi Taghizadeh, E-mail: mttaghizadeh@tabrizu.ac.ir
- Funds：
- DOI：10.1007/s10118-013-1247-2
  CLC：
- Received：26 June 2012，
  
  Revised：2012-09-11，
  
  Accepted：13 September 2012，
  
  Published：2013-04
- Accepted：
Scan QR Code
Mohamad Taghi Taghizadeh, Ali Bahadori. PREPARATION, CHARACTERIZATION AND ADHESIVE PROPERTIES OF DI-AND TRI-HYDROXY BENZOYL CHITOSAN NANOPARTICLES[J]. Chinese Journal of Polymer Science, 2013, 31(4): 649-659.
DOI：

Mohamad Taghi Taghizadeh, Ali Bahadori. PREPARATION, CHARACTERIZATION AND ADHESIVE PROPERTIES OF DI-AND TRI-HYDROXY BENZOYL CHITOSAN NANOPARTICLES[J]. Chinese Journal of Polymer Science, 2013, 31(4): 649-659. DOI： 10.1007/s10118-013-1247-2.

摘要

Abstract

Modified chitosans with 3

4-di-hydroxy benzoyl groups (CS-DHBA) and 3

5-tri-hydroxy benzoyl groups (CSTHBA) were synthesized and their nanoparticles were prepared

via

ionic crosslinking by tripolyphosphate (TPP). The chemical structure and degree of substitution (DS) of di- and tri-hydroxy benzoyl chitosans are determined by FTIR and

HNMR spectroscopy. The morphology of particles

size distribution and zeta potential of nanoparticles were studied using transmission electron microscopy (TEM) and dynamic light scattering (DLS)

respectively. The mean diameters of particles of CS-DHBA and CS-THBA nanoparticles were 144 nm and 112 nm

respectively. It was found that the particles size decreased slightly with decreasing the degree of substitution and increasing degree of deacetylation (DD)

due to increasing of ionic crosslinking of ammonium ions and polyanions of tripolyphosphate. The TEM photographs of CS-DHBA show that these particles are spherical in shape

but the particles of CS-THBA show some aggregation. In addition

the solubility and the mechanical properties of the prepared modified chitosans and their nanoparticles were evaluated for bio-adhesive and biomedical application. The results of solubility tests indicated that

the CS-DHBA and CS-THBA have higher solubility at pH

7 comparing to CS. Also the CS-DHBA

CS-THBA and their nanoparticles showed a significant adhesive capacity and enhanced tensile strength and tensile modulus.

关键词

Keywords

references

Views

Downloads

CSCD

Alert me when the article has been cited

Submit

Tools

Publicity Resources

Light-responsive Self-Immolative L-glutamic Acid-based Polyester Nanoparticles for Controlled Drug Release via Passerini Three-Component Polymerization

Improved Properties of Aromatic Polyamide Tape-casting Films

Synthesis and Physico-chemical Properties of (Co)polymers of 2-[(2E)-1-methyl-2-buten-1-yl]aniline and Aniline

Dispersion of Titanium(IV) Oxide Nanoparticles in Mixed Matrix Membrane Using Octaisobutyl Polyhedral Oligomeric Silsesquioxane for Enhanced CO2/CH4 Separation Performance

Optically Active Helical Poly(phenyl isocyanide)s Bearing Achiral Benzanilide Pendants: from Controlled Synthesis to Enantioseparation Application

Related Author

Qing-Fu Wang

Jing-Jiang Sun

Xiao-Fei Sun

Xu Zhang

Shu-Ping Song

Ya-Qun Yao

Yan Zhang

Cheng-Liang Wang

Related Institution

Qingdao Research Academy of Environmental Science

Key Laboratory of Rubber-plastics, Ministry of Education, School of Polymer Science and Engineering, Qingdao University of Science and Technology

Laboratory of Advanced Polymer Materials, Institute of Chemistry, Chinese Academy of Sciences

School of Chemical Sciences, University of Chinese Academy of Sciences

Ufa Institute of Chemistry, Russian Academy of Sciences, October Av, 71

⁰