IMPROVEMENT OF CREEP RESISTANCE OF POLYTETRAFLUOROETHYLENE FILMS BY NANO-INCLUSIONS
PAPER|Updated:2023-01-03
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IMPROVEMENT OF CREEP RESISTANCE OF POLYTETRAFLUOROETHYLENE FILMS BY NANO-INCLUSIONS
Chinese Journal of Polymer ScienceVol. 31, Issue 3, Pages: 377-387(2013)
Affiliations:
a.Key Laboratory for Polymeric Composite and Functional Materials of Ministry of Education, DSAPM Lab, School of Chemistry and Chemical Engineering, Sun Yat-sen (Zhongshan) University, Guangzhou 510275, China
b.Donghong Rubber & Plastics Products Company Ltd., Guangzhou 510530, China
c.Department of Polymer Engineering, Budapest University of Technology and Economics, H-1111 Budapest, Hungary
Xue-bo Shi, Chun-lei Wu, Min-zhi Rong, et al. IMPROVEMENT OF CREEP RESISTANCE OF POLYTETRAFLUOROETHYLENE FILMS BY NANO-INCLUSIONS[J]. Chinese Journal of Polymer Science, 2013, 31(3): 377-387.
DOI:
Xue-bo Shi, Chun-lei Wu, Min-zhi Rong, et al. IMPROVEMENT OF CREEP RESISTANCE OF POLYTETRAFLUOROETHYLENE FILMS BY NANO-INCLUSIONS[J]. Chinese Journal of Polymer Science, 2013, 31(3): 377-387.DOI: 10.1007/s10118-013-1225-8.
IMPROVEMENT OF CREEP RESISTANCE OF POLYTETRAFLUOROETHYLENE FILMS BY NANO-INCLUSIONS
To improve creep resistance of directional polytetrafluoroethylene (PTFE) films
epoxy grafted nano-SiO
2
is mixed with PTFE powder before sintering and calender rolling. The aligned macromolecular chains (especially those in amorphous region) of the composite films can be bundled up by the nanoparticles to share the applied stress together. In addition
incorporation of silica nanoparticles increases crystallinity of PTFE and favors microfibrillation of PTFE in the course of large deformation. As result
PTFE films exhibit lower creep strain and creep rate
and higher tensile strength and hardness. The work is believed to open an avenue for manufacturing high performance fluoropolymers by nano-inclusions.
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