DISPERSION PRODUCTION BY SEMI-CONTINUOUS RADICAL VINYL ACETATE EMULSION POLYMERIZATION WITH SILANE CO-MONOMER AND CHARACTERIZATION OF FINAL PRODUCTS

Mindaugas Dubininkas; Gintaras Buika

doi:10.1007/s10118-013-1220-0

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DISPERSION PRODUCTION BY SEMI-CONTINUOUS RADICAL VINYL ACETATE EMULSION POLYMERIZATION WITH SILANE CO-MONOMER AND CHARACTERIZATION OF FINAL PRODUCTS

PAPER | Updated：2023-01-03

- DISPERSION PRODUCTION BY SEMI-CONTINUOUS RADICAL VINYL ACETATE EMULSION POLYMERIZATION WITH SILANE CO-MONOMER AND CHARACTERIZATION OF FINAL PRODUCTS
- Chinese Journal of Polymer Science Vol. 31, Issue 2, Pages: 346-354(2013)
- Affiliations：
  
  Department of Organic Technology, Kaunas University of Technology, Radvilėnų pl. 19, LT-3028 Kaunas, Lithuania
- Author bio：
  
  *Mindaugas Dubininkas, E-mail: dubininkas@achema.com
- Funds：
- DOI：10.1007/s10118-013-1220-0
  CLC：
- Received：30 May 2012，
  
  Revised：2012-07-30，
  
  Accepted：07 August 2012，
  
  Published：2013-02
- Accepted：
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Mindaugas Dubininkas, Gintaras Buika. DISPERSION PRODUCTION BY SEMI-CONTINUOUS RADICAL VINYL ACETATE EMULSION POLYMERIZATION WITH SILANE CO-MONOMER AND CHARACTERIZATION OF FINAL PRODUCTS[J]. Chinese Journal of Polymer Science, 2013, 31(2): 346-354.
DOI：

Mindaugas Dubininkas, Gintaras Buika. DISPERSION PRODUCTION BY SEMI-CONTINUOUS RADICAL VINYL ACETATE EMULSION POLYMERIZATION WITH SILANE CO-MONOMER AND CHARACTERIZATION OF FINAL PRODUCTS[J]. Chinese Journal of Polymer Science, 2013, 31(2): 346-354. DOI： 10.1007/s10118-013-1220-0.

摘要

Abstract

Vinyl acetate radical emulsion polymerization in water with GF51 silane co-monomer was performed by semi continuous way. The GF51 impacts on dispersion rheology as well on films and bonding strength properties were determined. It should be stated that even low quantities of GF51 (up to 6% from VAc) determined high viscosity of dispersions. The GF51 modified films have low water absorption and high affinity to glass. Molecular mass and thermal properties of GF51 modified polymers were determined accordingly.

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