POLYROTAXANE WITH <italic style="font-style: italic">π</italic>-CONJUGATED PORPHYRIN AND POLYAZOMETHINE SYSTEMS PREPARED FROM A TYPE OF PORPHYRIN-DIALDEHYDE AND COMPLEX OF <italic style="font-style: italic">β</italic>-CYCLODEXTRIN WITH 1,4-PHENYLENEDIAMINE

Raziyeh Akbarzadeh; Hossein Dehghani

doi:10.1007/s10118-013-1198-7

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POLYROTAXANE WITH π-CONJUGATED PORPHYRIN AND POLYAZOMETHINE SYSTEMS PREPARED FROM A TYPE OF PORPHYRIN-DIALDEHYDE AND COMPLEX OF β-CYCLODEXTRIN WITH 1,4-PHENYLENEDIAMINE

PAPER | Updated：2023-01-03

- POLYROTAXANE WITH π-CONJUGATED PORPHYRIN AND POLYAZOMETHINE SYSTEMS PREPARED FROM A TYPE OF PORPHYRIN-DIALDEHYDE AND COMPLEX OF β-CYCLODEXTRIN WITH 1,4-PHENYLENEDIAMINE
- Chinese Journal of Polymer Science Vol. 31, Issue 1, Pages: 139-147(2013)
- Affiliations：
  
  Department of Inorganic Chemistry, Faculty of Chemistry, University of Kashan, P.O.Box 87317-51167 Kashan, Iran
- Author bio：
  
  *Hossein Dehghani, E-mail: Dehghani@kashanu.ac.ir
- Funds：
- DOI：10.1007/s10118-013-1198-7
  CLC：
- Received：09 February 2012，
  
  Revised：2012-04-17，
  
  Accepted：18 April 2012，
  
  Published：2013-01
- Accepted：
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Raziyeh Akbarzadeh, Hossein Dehghani. POLYROTAXANE WITH π-CONJUGATED PORPHYRIN AND POLYAZOMETHINE SYSTEMS PREPARED FROM A TYPE OF PORPHYRIN-DIALDEHYDE AND COMPLEX OF β-CYCLODEXTRIN WITH 1,4-PHENYLENEDIAMINE[J]. Chinese Journal of Polymer Science, 2013, 31(1): 139-147. DOI: 10.1007/s10118-013-1198-7.
DOI：

Raziyeh Akbarzadeh, Hossein Dehghani. POLYROTAXANE WITH π-CONJUGATED PORPHYRIN AND POLYAZOMETHINE SYSTEMS PREPARED FROM A TYPE OF PORPHYRIN-DIALDEHYDE AND COMPLEX OF β-CYCLODEXTRIN WITH 1,4-PHENYLENEDIAMINE[J]. Chinese Journal of Polymer Science, 2013, 31(1): 139-147. DOI: 10.1007/s10118-013-1198-7. DOI：

摘要

Abstract

The synthesis of 5

15-bis[4-(methoxycarbonyl)phenyl

]

-10

20-diphenylporphyrin (

) and its reduction to 5

15- bis[4-(hydroxymethyl)phenyl

]

-10

20-diphenylporphyrin (

)

and so its oxidation to provide 5

15-bis(4-formylphenyl)-10

20- diphenylporphyrin (

) are reported. The copolymer possessing

-cyclodextrin (

-CD)

-conjugated porphyrin and polyazomethine systems was synthesized by the polycondensation of porphyrin-dialdehyde monomer (

) and

- cyclodextrin/1

4-phenylenediamine complex (

). The monomers and the copolymer were characterized by UV-Vis

H-NMR and IR spectra. Furthermore

H-NMR and FT-IR spectra confirmed locating the aromatic ring of 1

4-phenylenediamine molecule in the center of

-cyclodextrin cavity.

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POLYROTAXANE WITH π-CONJUGATED PORPHYRIN AND POLYAZOMETHINE SYSTEMS PREPARED FROM A TYPE OF PORPHYRIN-DIALDEHYDE AND COMPLEX OF β-CYCLODEXTRIN WITH 1,4-PHENYLENEDIAMINE

DOI：10.1007/s10118-013-1198-7

摘要

Abstract

关键词

Keywords

references