PREPARATION OF SINGLE-HOLE HOLLOW POLYMER NANOSPHERES BY RASPBERRY-LIKE TEMPLATE METHOD

Yong Zhang; Jia-jia Chen; Geng-hui Zhang; Bai-zhu Chen; Hu-sheng Yan

doi:10.1007/s10118-013-1190-2

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PREPARATION OF SINGLE-HOLE HOLLOW POLYMER NANOSPHERES BY RASPBERRY-LIKE TEMPLATE METHOD

PAPER | Updated：2023-01-03

- PREPARATION OF SINGLE-HOLE HOLLOW POLYMER NANOSPHERES BY RASPBERRY-LIKE TEMPLATE METHOD
- Chinese Journal of Polymer Science Vol. 31, Issue 2, Pages: 294-301(2013)
- Affiliations：
  
  Key laboratory of Functional Polymer Materials (Ministry of Education), Institute of Polymer Chemistry, Nankai University, Tianjin 300071, China
- Author bio：
  
  **Hu-sheng Yan (阎虎生), E-mail: yanhs@nankai.edu.cn
- Funds：
- DOI：10.1007/s10118-013-1190-2
  CLC：
- Received：16 April 2012，
  
  Revised：2012-05-22，
  
  Accepted：30 May 2012，
  
  Published：2013-02
- Accepted：
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Yong Zhang, Jia-jia Chen, Geng-hui Zhang, et al. PREPARATION OF SINGLE-HOLE HOLLOW POLYMER NANOSPHERES BY RASPBERRY-LIKE TEMPLATE METHOD[J]. Chinese Journal of Polymer Science, 2013, 31(2): 294-301.
DOI：

Yong Zhang, Jia-jia Chen, Geng-hui Zhang, et al. PREPARATION OF SINGLE-HOLE HOLLOW POLYMER NANOSPHERES BY RASPBERRY-LIKE TEMPLATE METHOD[J]. Chinese Journal of Polymer Science, 2013, 31(2): 294-301. DOI： 10.1007/s10118-013-1190-2.

摘要

Abstract

Single-hole hollow polymer nanospheres were fabricated by raspberry-like template method using "graft-from" strategy through atom transfer radical polymerization (ATRP). Nanometer-sized silica spheres were covalently attached onto the surfaces of micrometer-sized silica spheres. Crosslinked polymer shells on the nano-sized spheres outside the attached area were formed by "graft-from" strategy through ATRP. After removal of the silica cores

single-hole hollow crosslinked polymer nanospheres were obtained. In this strategy

most of ATRP monomers may be used and thus many functional groups can be easily incorporated into the single-hole hollow crosslinked polymer nanospheres.

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