"SERGEANTS AND SOLDIERS RULE" IN HELICAL SUBSTITUTEDACETYLENE COPOLYMER EMULSIONS

Xuan Liu; Ci Song; Xiao-feng Luo; Wan-tai Yang; Jian-ping Deng

doi:10.1007/s10118-013-1189-8

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"SERGEANTS AND SOLDIERS RULE" IN HELICAL SUBSTITUTEDACETYLENE COPOLYMER EMULSIONS

PAPER | Updated：2023-01-03

- "SERGEANTS AND SOLDIERS RULE" IN HELICAL SUBSTITUTEDACETYLENE COPOLYMER EMULSIONS
- Chinese Journal of Polymer Science Vol. 31, Issue 1, Pages: 179-186(2013)
- Affiliations：
  
  State Key Laboratory of Chemical Resource Engineering, College of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, China
- Author bio：
  
  **Jian-ping Deng (邓建平), E-mail: dengjp@mail.buct.edu.cn
- Funds：
- DOI：10.1007/s10118-013-1189-8
  CLC：
- Received：14 March 2012，
  
  Revised：2012-04-23，
  
  Accepted：25 April 2012，
  
  Published：2013-01
- Accepted：
Scan QR Code
Xuan Liu, Ci Song, Xiao-feng Luo, et al. "SERGEANTS AND SOLDIERS RULE" IN HELICAL SUBSTITUTEDACETYLENE COPOLYMER EMULSIONS[J]. Chinese Journal of Polymer Science, 2013, 31(1): 179-186.
DOI：

Xuan Liu, Ci Song, Xiao-feng Luo, et al. "SERGEANTS AND SOLDIERS RULE" IN HELICAL SUBSTITUTEDACETYLENE COPOLYMER EMULSIONS[J]. Chinese Journal of Polymer Science, 2013, 31(1): 179-186. DOI： 10.1007/s10118-013-1189-8.

摘要

Abstract

The "sergeants and soldiers rule" occurring in helical copolymer emulsions derived from an achiral monomer (M1) and a chiral monomer (M2) was observed. TEM

GPC

and

H-NMR techniques in combination demonstrate the formation of nanoparticles constituted by the copolymers. CD and UV-Vis spectra show the (co)polymer chains in the nanoparticles adopt helical structures of a predominant helicity

and the copolymers follow the "sergeants and soldiers rule" in forming helical structure.

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