SPECTRAL AND CHEMICAL MONITORING OF CYCLO-ADDITION REACTION OF CO<sub>2</sub> WITH POLY(MMA-<italic style="font-style: italic">co</italic>-GMA) COPOLYMERS

M. Yadollahi; H. Bouhendi; M.J. Zohuriaan-Mehr; K. Kabiri

doi:10.1007/s10118-012-1174-7

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SPECTRAL AND CHEMICAL MONITORING OF CYCLO-ADDITION REACTION OF CO₂ WITH POLY(MMA-co-GMA) COPOLYMERS

PAPER | Updated：2023-01-03

- SPECTRAL AND CHEMICAL MONITORING OF CYCLO-ADDITION REACTION OF CO₂ WITH POLY(MMA-co-GMA) COPOLYMERS
- Chinese Journal of Polymer Science Vol. 30, Issue 5, Pages: 727-734(2012)
- Affiliations：
  
  Iran Polymer and Petrochemical Institute (IPPI), P.O. Box 14965-115, Tehran, Iran
- Author bio：
  
  *H. Bouhendi, E-mail: H.Boohendi@ippi.ac.ir
- Funds：
- DOI：10.1007/s10118-012-1174-7
  CLC：
- Received：12 December 2011，
  
  Revised：2012-02-04，
  
  Accepted：27 February 2012，
  
  Published：2012-09
- Accepted：
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M. Yadollahi, H. Bouhendi, M.J. Zohuriaan-Mehr, et al. SPECTRAL AND CHEMICAL MONITORING OF CYCLO-ADDITION REACTION OF CO₂ WITH POLY(MMA-co-GMA) COPOLYMERS[J]. Chinese Journal of Polymer Science, 2012, 30(5): 727-734. DOI: 10.1007/s10118-012-1174-7.
DOI：

M. Yadollahi, H. Bouhendi, M.J. Zohuriaan-Mehr, et al. SPECTRAL AND CHEMICAL MONITORING OF CYCLO-ADDITION REACTION OF CO₂ WITH POLY(MMA-co-GMA) COPOLYMERS[J]. Chinese Journal of Polymer Science, 2012, 30(5): 727-734. DOI: 10.1007/s10118-012-1174-7. DOI：

摘要

Abstract

This paper deals with the monitoring cyclo-addition of CO

to methyl methacrylate (MMA)-glycidyl methacrylate (GMA) copolymers using spectral (

H-NMR and FTIR) and chemical (elemental analysis and titration) methods. Thus

poly(MMA-

-GMA)

was first prepared

via

solution polymerization. The copolymer was then treated with CO

gas flow in the presence of cetyltrimethyl ammoniumbromide as a catalyst. In terms of the carbonation reaction time

the terpolymer poly(MMA-

-GMA-

-2-oxo-1

3-dioxolane-4-yl-methyl methacrylate) was prepared in various yield of CO

fixation (

90%). The peak intensity changes in the

H-NMR and FTIR spectra provided excellent demonstrative techniques to monitor the carbonation reaction progression. In a comparative analytical viewpoint

the NMR and elemental analysis were recognized to be the most accurate ways to follow the cyclo-addition reaction progression. However

titration was recognized to be the most preferred method

because it is a very inexpensive

facile and available method with a reasonable costaccuracy balance.

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SPECTRAL AND CHEMICAL MONITORING OF CYCLO-ADDITION REACTION OF CO2 WITH POLY(MMA-co-GMA) COPOLYMERS

DOI：10.1007/s10118-012-1174-7

摘要

Abstract

关键词

Keywords

references

SPECTRAL AND CHEMICAL MONITORING OF CYCLO-ADDITION REACTION OF CO₂ WITH POLY(MMA-co-GMA) COPOLYMERS