SYNTHESIS AND CHARACTERIZATION OF Fe(II)-COORDINATED PS-<italic style="font-style: italic">b</italic>-P[NIPAM-<italic style="font-style: italic">co</italic>-(VBC-Fe-DMAP)] BLOCK COPOLYMERS

Kai Cao; Jun-ting Xu; Xiao-song Wang

doi:10.1007/s10118-012-1161-z

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SYNTHESIS AND CHARACTERIZATION OF Fe(II)-COORDINATED PS-b-P[NIPAM-co-(VBC-Fe-DMAP)] BLOCK COPOLYMERS

PAPER | Updated：2023-01-03

- SYNTHESIS AND CHARACTERIZATION OF Fe(II)-COORDINATED PS-b-P[NIPAM-co-(VBC-Fe-DMAP)] BLOCK COPOLYMERS
- Chinese Journal of Polymer Science Vol. 30, Issue 5, Pages: 674-681(2012)
- Affiliations：
  
  a.Department of Materials Science and Engineering, East China University of Science and Technology, Shanghai 200237, China
  b.MOE key Laboratory of Macromolecular Synthesis and Functionalization, Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027, China
  c.Department of Chemistry, Waterloo Institute of Nanotechnology, University of Waterloo, 200 University Avenue West Waterloo, ON N2L 3G1, Canada
- Author bio：
  
  **Jun-ting Xu (徐君庭), E-mail: xujt@zju.edu.cn
  Xiao-song Wang (王晓松), E-mail: xiaosong.wang@uwaterloo.ca
- Funds：
- DOI：10.1007/s10118-012-1161-z
  CLC：
- Received：08 November 2011，
  
  Revised：2012-01-05，
  
  Accepted：01 February 2012，
  
  Published：2012-09
- Accepted：
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Kai Cao, Jun-ting Xu, Xiao-song Wang. SYNTHESIS AND CHARACTERIZATION OF Fe(II)-COORDINATED PS-b-P[NIPAM-co-(VBC-Fe-DMAP)] BLOCK COPOLYMERS[J]. Chinese Journal of Polymer Science, 2012, 30(5): 674-681. DOI: 10.1007/s10118-012-1161-z.
DOI：

Kai Cao, Jun-ting Xu, Xiao-song Wang. SYNTHESIS AND CHARACTERIZATION OF Fe(II)-COORDINATED PS-b-P[NIPAM-co-(VBC-Fe-DMAP)] BLOCK COPOLYMERS[J]. Chinese Journal of Polymer Science, 2012, 30(5): 674-681. DOI: 10.1007/s10118-012-1161-z. DOI：

摘要

Abstract

In this work

a new type of block polymers

polystyrene-

-poly[(

-isopropyl acrylamide)-co-(vinyl benzyl chloride)] (PS-

-P(NIPAM-

-VBC))

was prepared

via

reversible addition fragmentation transfer polymerization

then pentacyano(4-(dimethylamino pyridine))ferrate (Fe-DMAP) was attached to VBC units through a quaternization process. The Fe(II)-coordinated PS-

-P[NIPAM-

-(VBC-Fe-DMAP)] block copolymers were characterized by

H-NMR

FT-IR and TGA. The self-assembly behavior of the block copolymers was also investigated and the micelle morphology was characterized by TEM. It was found that the PS-

-P(NIPAM-

-VBC) block polymer and Fe-coordinated block copolymer could both form spherical micelles in DMF/MeOH mixed solvent.

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Related Institution

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SYNTHESIS AND CHARACTERIZATION OF Fe(II)-COORDINATED PS-b-P[NIPAM-co-(VBC-Fe-DMAP)] BLOCK COPOLYMERS

DOI：10.1007/s10118-012-1161-z

摘要

Abstract

关键词

Keywords

references