Shu-hong Li, Lei Fang, Rui Wang, et al. SILICON-CONTAINING POLY(p-ARYLENE VINYLENE)S: SYNTHESIS AND PHOTOPHYSICS. [J]. Chinese Journal of Polymer Science 30(4):589-594(2012)
DOI:
Shu-hong Li, Lei Fang, Rui Wang, et al. SILICON-CONTAINING POLY(p-ARYLENE VINYLENE)S: SYNTHESIS AND PHOTOPHYSICS. [J]. Chinese Journal of Polymer Science 30(4):589-594(2012) DOI: 10.1007/s10118-012-1157-8.
SILICON-CONTAINING POLY(p-ARYLENE VINYLENE)S: SYNTHESIS AND PHOTOPHYSICS
A series of new silicon-containing poly(,p,-arylene vinylene)s (PAVs) with anthracene units in the main chain were synthesized by hydrosilylation reaction. The introduction of organosilicon units improved the solubility of the polymers, and the π-π conjugation of polymeric chains was interrupted. These polymers behaved as blue-green light emitters with their fluorescence maximum at 447-499 nm and quantum yields in the range of 0.28-0.30 in solution.