INFLUENCE OF SHEARING ON IMPACT POLYPROPYLENE COPOLYMER: PHASE MORPHOLOGY, THERMAL AND RHEOLOGICAL BEHAVIOR

Yi Wu; Xian-yuan Liang; Rui-fen Chen; Yong-gang Shangguan; Qiang Zheng

doi:10.1007/s10118-012-1145-z

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INFLUENCE OF SHEARING ON IMPACT POLYPROPYLENE COPOLYMER: PHASE MORPHOLOGY, THERMAL AND RHEOLOGICAL BEHAVIOR

PAPER | Updated：2023-01-03

- INFLUENCE OF SHEARING ON IMPACT POLYPROPYLENE COPOLYMER: PHASE MORPHOLOGY, THERMAL AND RHEOLOGICAL BEHAVIOR
- Chinese Journal of Polymer Science Vol. 30, Issue 3, Pages: 470-477(2012)
- Affiliations：
  
  a.School of Traffic and Automobile Engineering, Xihua University, Chengdu 610039, China
  b.Key Laboratory of Macromolecular Synthesis and Functionalization, Ministry of Education, Hangzhou 310027, China
  c.Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027, China
- Author bio：
  
  **Yi Wu (吴怡), E-mail: xinyi7711@163.com
  Qiang Zheng (郑强), E-mail: zhengqiang@zju.edu.cn
- Funds：
- DOI：10.1007/s10118-012-1145-z
  CLC：
- Received：12 October 2011，
  
  Revised：2011-11-17，
  
  Accepted：21 November 2011，
  
  Published：2012-05
- Accepted：
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Yi Wu, Xian-yuan Liang, Rui-fen Chen, et al. INFLUENCE OF SHEARING ON IMPACT POLYPROPYLENE COPOLYMER: PHASE MORPHOLOGY, THERMAL AND RHEOLOGICAL BEHAVIOR[J]. Chinese Journal of Polymer Science, 2012, 30(3): 470-477.
DOI：

Yi Wu, Xian-yuan Liang, Rui-fen Chen, et al. INFLUENCE OF SHEARING ON IMPACT POLYPROPYLENE COPOLYMER: PHASE MORPHOLOGY, THERMAL AND RHEOLOGICAL BEHAVIOR[J]. Chinese Journal of Polymer Science, 2012, 30(3): 470-477. DOI： 10.1007/s10118-012-1145-z.

摘要

Abstract

The influences of shearing conducted by a Brabender rheometer on phase morphology

thermal and rheological behavior of a commercial impact polypropylene copolymer (IPC) were studied. The crystallization and melting traces show that short-time annealing at 210℃ is unable to completely erase the influence of shearing on the samples. When the samples which were treated at a rotation speed of 80 r/min crystallize at a cooling rate of 10 K/min

their

s and corresponding

s obviously rise with the increase of shearing time. Furthermore

the POM results reveal that the shearing can lead to the formation of shish-kebab and the shish-kebab amount is proportional to shearing time. The rheological measurement results show that the treated samples exhibit different

′~

dependences. The 'second plateau’ appears when the sample is treated at a rotation speed of 60 r/min or 80 r/min for 10 min

and linear

′~

dependence is observed at other rotation speeds. In addition

it is found that the appearance of the 'second plateau’ depends on the shearing time when the rotation speed is fixed. According to SEM observations

it is proposed that the 'second plateau’ of IPC samples should be ascribed to the aggregation of dispersion particles.

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