SYNTHESIS AND CHARACTERIZATION OF POLYBENZOXAZINE CONTAINING PHOSPHORUS

Ting-ting Zhang; Wei-wei Men; Ying Liu; Zai-jun Lu

doi:10.1007/s10118-012-1115-5

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SYNTHESIS AND CHARACTERIZATION OF POLYBENZOXAZINE CONTAINING PHOSPHORUS

PAPER | Updated：2023-01-03

- SYNTHESIS AND CHARACTERIZATION OF POLYBENZOXAZINE CONTAINING PHOSPHORUS
- Chinese Journal of Polymer Science Vol. 30, Issue 2, Pages: 250-257(2012)
- Affiliations：
  
  Key Laboratory for Special Functional Aggregated Materials of Ministry of Education, School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China
- Author bio：
  
  **Zai-jun Lu (鲁在君), E-mail: z.lu@sdu.edu.cn.
- Funds：
- DOI：10.1007/s10118-012-1115-5
  CLC：
- Received：30 March 2011，
  
  Revised：2011-05-20，
  
  Accepted：31 May 2011，
  
  Published：2012-03
- Accepted：
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Ting-ting Zhang, Wei-wei Men, Ying Liu, et al. SYNTHESIS AND CHARACTERIZATION OF POLYBENZOXAZINE CONTAINING PHOSPHORUS[J]. Chinese Journal of Polymer Science, 2012, 30(2): 250-257.
DOI：

Ting-ting Zhang, Wei-wei Men, Ying Liu, et al. SYNTHESIS AND CHARACTERIZATION OF POLYBENZOXAZINE CONTAINING PHOSPHORUS[J]. Chinese Journal of Polymer Science, 2012, 30(2): 250-257. DOI： 10.1007/s10118-012-1115-5.

摘要

Abstract

The novel benzoxazine monomer containing phosphorus has been synthesized based on multifunctional amine route from bis(4-aminophenyl)phenylphosphate

-cresol and formaldehyde. Subsequently

the benzoxazine monomer was thermo-cured into polybenzoxazine containing phosphorus. The chemical structures were identified by nuclear magnetic resonance (NMR)

Fourier transform infrared spectroscopy (FT-IR). The curing reaction was monitored by differential scanning calorimetry (DSC) and FT-IR. The thermal and flame-retardant properties of obtained polybenzoxazine were evaluated by dynamic mechanical thermal analysis (DMA)

thermal gravimetric analysis (TGA) and oxygen index meter

respectively. The results show that the novel polybenzoxazine has high limiting oxygen index (38.1) and glass transition temperature (232℃).

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