AZIDE-ALKYNE CLICK POLYMERIZATION: AN UPDATE

Hong-kun Li; Jing-zhi Sun; An-jun Qin; Ben Zhong Tang

doi:10.1007/s10118-012-1098-2

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AZIDE-ALKYNE CLICK POLYMERIZATION: AN UPDATE

Review | Updated：2023-01-03

- AZIDE-ALKYNE CLICK POLYMERIZATION: AN UPDATE
- Chinese Journal of Polymer Science Vol. 30, Issue 1, Pages: 1-15(2012)
- Affiliations：
  
  a.MOE Key Laboratory of Macromolecular Synthesis and Functionalization, Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027, China
  b.Department of Chemistry, Institute of Molecular Functional Materials, The Hong Kong University of Science & Technology, Clear Water Bay, Kowloon, Hong Kong, China
- Author bio：
  
  **An-jun Qin (秦安军), E-mail: qinaj@zju.edu.cn
  Ben Zhong Tang (唐本忠), E-mail: tangbenz@ust.hk
- Funds：
- DOI：10.1007/s10118-012-1098-2
  CLC：
- Received：27 June 2011，
  
  Revised：2011-07-15，
  
  Accepted：19 July 2011，
  
  Published：2012-01
- Accepted：
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Hong-kun Li, Jing-zhi Sun, An-jun Qin, et al. AZIDE-ALKYNE CLICK POLYMERIZATION: AN UPDATE[J]. Chinese Journal of Polymer Science, 2012, 30(1): 1-15.
DOI：

Hong-kun Li, Jing-zhi Sun, An-jun Qin, et al. AZIDE-ALKYNE CLICK POLYMERIZATION: AN UPDATE[J]. Chinese Journal of Polymer Science, 2012, 30(1): 1-15. DOI： 10.1007/s10118-012-1098-2.

摘要

Abstract

The great achievements of click chemistry have encouraged polymer scientists to use this reaction in their field. This review assembles an update of the advances of using azide-alkyne click polymerization to prepare functional polytriazoles (PTAs) with linear and hyperbranched structures. The Cu(I)-mediated click polymerization furnishes 1

4-regioregular PTAs

whereas

the metal-free click polymerization of propiolates and azides produces PTAs with 1

4-regioisomer contents up to 90%. The PTAs display advanced functions

such as aggregation-induced emission

thermal stability

biocompatibility and optical nonlinearity.

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