Chun-hui Zhang, Rui-fen Chen, Feng Chen, et al. STUDY ON HIGH WELD STRENGTH OF IMPACT PROPYLENE COPOLYMER/HIGH DENSITY POLYETHYLENE LAMINATES[J]. Chinese Journal of Polymer Science, 2011, 29(4): 497-505.
DOI:
Chun-hui Zhang, Rui-fen Chen, Feng Chen, et al. STUDY ON HIGH WELD STRENGTH OF IMPACT PROPYLENE COPOLYMER/HIGH DENSITY POLYETHYLENE LAMINATES[J]. Chinese Journal of Polymer Science, 2011, 29(4): 497-505.DOI: 10.1007/s10118-011-1059-1.
STUDY ON HIGH WELD STRENGTH OF IMPACT PROPYLENE COPOLYMER/HIGH DENSITY POLYETHYLENE LAMINATES
The impact propylene copolymer (IPC) and isotactic polypropylene (
i
PP) were separately selected to prepare laminates with high density polyethylene (HDPE) by hot press. The peel forces of IPC/HDPE and
i
PP/HDPE laminates were examined
and it was found that the welded joint strength in IPC/HDPE laminate was dramatically higher than that of
i
PP/HDPE laminate. According to the special microstructure of IPC
the co-crystallization of the ethylene segments in ethylene-propylene block copolymer (E
b
P) component of IPC and the PE chain in HDPE was proposed to explain the high-strength welding. The DSC results indicated that there indeed existed some interaction between IPC and HDPE
and the crystallizable PE component in IPC could affect the crystallization of HDPE. The scanning electron microscope (SEM) observations of IPC/HDPE blends demonstrated that HDPE tended to stay with the PE-rich E
b
P chains to form the dispersed phase
indicating the good miscibility between HDPE and E
b
P components of IPC. According to the above results
the effect of co-crystallization of the PE components of the IPC and HDPE on the high weld strength of IPC/HDPE laminate was confirmed.
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