Kun Jiang, Fei-long Yu, Run Su, et al. HIGH SPEED INJECTION MOLDING OF HIGH DENSITY POLYETHYLENE —EFFECTS OF INJECTION SPEED ON STRUCTURE AND PROPERTIES[J]. Chinese Journal of Polymer Science, 2011, 29(4): 456-464.
DOI:
Kun Jiang, Fei-long Yu, Run Su, et al. HIGH SPEED INJECTION MOLDING OF HIGH DENSITY POLYETHYLENE —EFFECTS OF INJECTION SPEED ON STRUCTURE AND PROPERTIES[J]. Chinese Journal of Polymer Science, 2011, 29(4): 456-464.DOI: 10.1007/s10118-011-1049-3.
HIGH SPEED INJECTION MOLDING OF HIGH DENSITY POLYETHYLENE —EFFECTS OF INJECTION SPEED ON STRUCTURE AND PROPERTIES
Thin wall samples of high density polyethylene (HDPE) were prepared
via
injection molding with different injection speeds ranging from 100 mm/s to 1200 mm/s. A significant decrease in the tensile strength and Young’s modulus was observed with increasing injection speed. In order to investigate the mechanism behind this decrease
the orientation
molecular weight
molecular weight distribution
melt flow rate
crystallinity and crystal morphology of HDPE were characterized using two-dimensional wide-angle X-ray diffraction (2D-WAXD)
gel permeation chromatography (GPC)
capillary rheometry and differential scanning calorimetry (DSC)
respectively. It is demonstrated that the orientation
molecular weight
molecular weight distribution
melt flow rate and crystallinity have no obvious change with increasing injection speed. Nevertheless
the content of extended chain crystals or large folded chain crystals was found to decrease with increasing injection speed. Therefore
it is concluded that the decrease in tensile properties is mainly contributed by the reduced content of extended chain crystals or large folded chain crystals. This study provides industry with valuable information for the application of high speed injection molding.
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