SYNTHESIS OF POLYELECTROLYTIC POLYACETYLENE DERIVATIVES BY QUATERNIZATION OF POLY(PYRIDYLACETYLENE)

Yu Mao; Xiao-a Zhang; Hai-peng Xu; Wang-zhang Yuan; Hui Zhao; An-jun Qin; Jing-zhi Sun; Ben Zhong Tang

doi:10.1007/s10118-011-1032-z

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SYNTHESIS OF POLYELECTROLYTIC POLYACETYLENE DERIVATIVES BY QUATERNIZATION OF POLY(PYRIDYLACETYLENE)

Rapid Communication | Updated：2021-06-21

- SYNTHESIS OF POLYELECTROLYTIC POLYACETYLENE DERIVATIVES BY QUATERNIZATION OF POLY(PYRIDYLACETYLENE)
- Chinese Journal of Polymer Science Vol. 29, Issue 2, Pages: 133-140(2011)
- Affiliations：
  
  a.Department of Polymer Science and Engineering, MOE of Key Laboratory of Macromolecular Synthesis and Functionalization, Zhejiang University, Hangzhou 310027, China
  b.Department of Chemistry, The Hong Kong University of Science & Technology, Clear Water Bay, Kowloon, Hong Kong, China
- Author bio：
  
  **Jing-zhi Sun (孙景志), E-mail: sunjz@zju.edu.cn
  Ben Zhong Tang (唐本忠), E-mail: tangbenz@ust.hk
- Funds：
- DOI：10.1007/s10118-011-1032-z
  CLC：
- Received：30 November 2010，
  
  Revised：2010-12-14，
  
  Accepted：20 December 2010，
  
  Published：2011
- Accepted：
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Yu Mao, Xiao-a Zhang, Hai-peng Xu, et al. SYNTHESIS OF POLYELECTROLYTIC POLYACETYLENE DERIVATIVES BY QUATERNIZATION OF POLY(PYRIDYLACETYLENE)[J]. Chinese Journal of Polymer Science, 2011, 29(2): 133-140.
DOI：

Yu Mao, Xiao-a Zhang, Hai-peng Xu, et al. SYNTHESIS OF POLYELECTROLYTIC POLYACETYLENE DERIVATIVES BY QUATERNIZATION OF POLY(PYRIDYLACETYLENE)[J]. Chinese Journal of Polymer Science, 2011, 29(2): 133-140. DOI： 10.1007/s10118-011-1032-z.

摘要

Abstract

Functional polyacetylenes containing pyridinium side groups (PPyA-MX

X = Br and I) were successfully synthesized. Spectroscopic techniques such as

H-NMR

C-NMR

and FTIR spectroscopy were used to characterize the structure of the obtained polymers. The characterization data were well consistent with the expected macromolecular structures. PPyA-MI had good solubility in polar organic solvents and low solubility in water

while PPyA-MBr had good solubility in both polar organic solvents and water.

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