SYNTHESIS OF HETEROARM STAR POLYMERS COMPRISING POLY(4-METHYLPHENYL VINYL SULFOXIDE) SEGMENT BY LIVING ANIONIC POLYMERIZATION

Qiang Liu a; You-ke Huang a; Xiang-dong Zhou b; You-liang Zhao a

doi:10.1007/s10118-010-9166-y

Your Location：

Home >

Browse articles >

SYNTHESIS OF HETEROARM STAR POLYMERS COMPRISING POLY(4-METHYLPHENYL VINYL SULFOXIDE) SEGMENT BY LIVING ANIONIC POLYMERIZATION

Papers | Updated：2021-06-21

- SYNTHESIS OF HETEROARM STAR POLYMERS COMPRISING POLY(4-METHYLPHENYL VINYL SULFOXIDE) SEGMENT BY LIVING ANIONIC POLYMERIZATION
- Vol. 28, Issue 5, Pages: 819-828(2010)
- Affiliations：
- Author bio：
- Funds：
- DOI：10.1007/s10118-010-9166-y
  CLC：
- Published：20 September 2010
- Accepted：
Scan QR Code
Qiang Liu a, You-ke Huang a, Xiang-dong Zhou b, et al. SYNTHESIS OF HETEROARM STAR POLYMERS COMPRISING POLY(4-METHYLPHENYL VINYL SULFOXIDE) SEGMENT BY LIVING ANIONIC POLYMERIZATION[J]. 2010, 28(5): 819-828.
DOI：

Qiang Liu a, You-ke Huang a, Xiang-dong Zhou b, et al. SYNTHESIS OF HETEROARM STAR POLYMERS COMPRISING POLY(4-METHYLPHENYL VINYL SULFOXIDE) SEGMENT BY LIVING ANIONIC POLYMERIZATION[J]. 2010, 28(5): 819-828. DOI： 10.1007/s10118-010-9166-y.

摘要

A series of 3-arm ABC and AA'B and 4-arm ABCD

AA'BC and AA'A"B heteroarm star polymers comprising one poly(4-methylphenyl vinyl sulfoxide) segment and other segments such as polystyrene

poly(α-methylstyrene)

poly(4-methoxystyrene) and poly(4-trimethylsilylstyrene) were synthesized by living anionic polymerization based on diphenylethylene (DPE) chemistry. The DPE-functionalized polymers were synthesized by iterative methodology

and the objective star polymers were prepared by two distinct methodologies based on anionic polymerization using DPE-functionalized polymers. The first methodology involves an addition reaction of living anionic polymer with excess DPE-functionalized polymer and a subsequent living anionic polymerization of 4-methylphenyl vinyl sulfoxide (MePVSO) initiated from the in situ formed polymer anion with two or three polymer segments. The second methodology comprises an addition reaction of DPE-functionalized polymer with excess sec-BuLi and a following anionic polymerization of MePVSO initiated from the in situ formed polymer anion and 3-methyl-1

1-diphenylpentyl anion as well. Both approaches could afford the target heteroarm star polymers with predetermined molecular weight

narrow molecular weight distribution (Mw/Mn 1.03) and desired composition

evidenced by SEC

1H-NMR and SLS analyses. These polymers can be used as model polymers to investigate structure-property relationships in heteroarm star polymers.

Abstract

A series of 3-arm ABC and AA'B and 4-arm ABCD

AA'BC and AA'A"B heteroarm star polymers comprising one poly(4-methylphenyl vinyl sulfoxide) segment and other segments such as polystyrene

poly(α-methylstyrene)

1-diphenylpentyl anion as well. Both approaches could afford the target heteroarm star polymers with predetermined molecular weight

narrow molecular weight distribution (Mw/Mn 1.03) and desired composition

evidenced by SEC

1H-NMR and SLS analyses. These polymers can be used as model polymers to investigate structure-property relationships in heteroarm star polymers.

关键词

Keywords

references

Views

Downloads

CSCD

Alert me when the article has been cited

Submit

Tools

Publicity Resources

Circularly Polarized Luminescence Based on Helical Polymers: Structure-Property Relationships and Regulation Mechanisms

2026-9 Contents

Bioinspired Zinc-doped Nano Hydroxyapatite Reinforced Poly(lactic acid) Composites for Bone Repair

Pyrimidoisoindigo-based Polymers for Ambipolar Charge Transport

Highly Regio- and trans-Selective Ring-opening Metathesis Polymerization of Chiral Aza-norbornene with a Simple Phenylimido-Tungsten Catalyst

Related Author

No data

Related Institution

No data

⁰